A combined spectroscopic, photophysical and theoretical (DFT) study of the electronically excited inorganometallic complexes Ru(E)(E')(CO)₂(iPr-DAB): Detection and characterization of an exceptionally long-lived ³σπ* excited state for Ru(SnPh₃)₂(CO)₂(iPr-DAB). (E=Cl, Me, SnPh₃, PbPh₃; E'=GePh₃, SnPh₃, PbPh₃ (R=Me, Ph); iPr-DAB = N,N'-diisopropyl-1,4-diaza-1,3-butadiene).

M.P. Aarnts, D.J. Stufkens, M.P. Wilms, E.J. Baerends, A. Jr. Vlcek, I.P. Clark, M.W. George, J.J. Turner

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