A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

L. Botez, J.C. Slootweg, Berth-Jan Deelman

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 % by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.
Original languageEnglish
Pages (from-to)434-437
Number of pages4
JournalEuropean Journal of Organic Chemistry
Volume2017
Issue number3
DOIs
Publication statusPublished - 2017

Funding

We gratefully thank the European Union (Marie Curie ITN SusPhos, Grant Agreement No. 317404) for financial support. We thank Ben Bruyneel and Elwin Jansen (Vrije Universiteit Amsterdam) for measuring high-resolution mass spectra and Prof. Dr. K. Lammertsma for his generous support.

FundersFunder number
European Commission317404

    Keywords

    • phosphinate

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