A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

L. Botez, J.C. Slootweg, Berth-Jan Deelman

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 % by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.
Original languageEnglish
Pages (from-to)434-437
JournalEuropean Journal of Organic Chemistry
Volume2017
Issue number3
DOIs
Publication statusPublished - 2017

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Sodium
sodium
acids
Acids
synthesis
Catalysis
hazards
catalysis
reagents
Hazards
routes

Keywords

  • phosphinate

Cite this

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abstract = "Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 {\%} by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.",
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A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate. / Botez, L.; Slootweg, J.C.; Deelman, Berth-Jan .

In: European Journal of Organic Chemistry, Vol. 2017, No. 3, 2017, p. 434-437.

Research output: Contribution to JournalArticleAcademicpeer-review

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AU - Slootweg, J.C.

AU - Deelman, Berth-Jan

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AB - Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 % by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.

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U2 - 10.1002/ejoc.201601222

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