A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

L. Botez; J.C. Slootweg; Berth-Jan  Deelman

doi:10.1002/ejoc.201601222

A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

L. Botez, J.C. Slootweg, Berth-Jan Deelman

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 % by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.

Original language	English
Pages (from-to)	434-437
Number of pages	4
Journal	European Journal of Organic Chemistry
Volume	2017
Issue number	3
DOIs	https://doi.org/10.1002/ejoc.201601222
Publication status	Published - 2017

Keywords

phosphinate

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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abstract = "Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 % by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.",

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AU - Slootweg, J.C.

AU - Deelman, Berth-Jan

PY - 2017

Y1 - 2017

N2 - Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 % by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.

AB - Widely available, hazard-free sodium phosphinate directly furnishes sodium diarylphosphinates and their corresponding acids in yields up to 86 % by using Pd-catalysis. This versatile method tolerates moieties such as keto and carboxyl, incompatible with the classical Grignard or organolithium reagents. This route also eliminates the need for PCl3 and alkyl- or ammoniumphosphinates.

KW - phosphinate

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SN - 1434-193X

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A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

Abstract

Keywords

UN SDGs

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