A Network Approach for the Accurate Characterization of Water Lines Observable in Astronomical Masers and Extragalactic Environments

The water molecule, crucial to the chemical composition and dynamics of the universe, is typically identified in its gas phase via radio and submillimeter transitions, with frequencies up to a few THz. To understand the physicochemical behavior of astronomical objects, accurate transition frequencies are required for these lines. From a set of 26 new and 564 previous Lamb dip measurements, utilizing our ultrasensitive laser-based spectrometers in the near-infrared region, ultrahigh-precision spectroscopic networks were set up for H₂¹⁶O and H₂¹⁸O, augmented with 40 extremely accurate frequencies taken from the literature. Based on kHz-accuracy paths of these networks, considerably improved line-center frequencies have been obtained for 35 observed or predicted maser lines of H₂¹⁶O, as well as for 14 transitions of astronomical significance of H₂¹⁸O. These reference frequencies, attached with 5-25 kHz uncertainties, may help future studies in various fields of astrochemistry and astrophysics, in particular when precise information is demanded about Doppler-velocity components, including the gas flows of galactic cores, the kinematics of planetary nebulae, or the motion in exoplanetary atmospheres.