Acetylene-substituted phosphane oxides: Building blocks for macrocycles

S.G.A. van Assema, G.T. de Jong, A.W. Ehlers, F.J.J. de Kanter, M. Schakel, A.L Spek, M. Lutz, K. Lammertsma

Research output: Contribution to JournalArticleAcademicpeer-review


Phosphorus-based macrocycles with acetylenic scaffolds have been built from acetylene-substituted phosphane oxides that were formed from diisopropylphosphoramidic dibromide (3) and an acetylenic Grignard reagent. The four-and six-edged macrocycles 15 and 16, in which the iPr
Original languageEnglish
Pages (from-to)2405-2412
JournalEuropean Journal of Organic Chemistry
Issue number15
Publication statusPublished - 2007


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