Activation of the C-H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)(2+)/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System

C. Michel; P. Belanzoni; P. Gamez; J. Reedijk; E.J. Baerends

doi:10.1021/ic902155m

Activation of the C-H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)(2+)/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System

C. Michel, P. Belanzoni, P. Gamez, J. Reedijk, E.J. Baerends

Theoretical Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

We have investigated the reaction mechanism of the selective aerobic oxidation of primary alcohols into aldehydes using a bipy-copper complex and the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) radical as cocatalysts (Gamez et al. Chem. Commun. 2003, 2412-2415) and compared it to the well-known oxidation by the TEMPO

Original language	English
Pages (from-to)	11909-11920
Journal	Inorganic Chemistry
Volume	48
Issue number	24
DOIs	https://doi.org/10.1021/ic902155m
Publication status	Published - 2009

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Michel, C., Belanzoni, P., Gamez, P., Reedijk, J., & Baerends, E. J. (2009). Activation of the C-H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)(2+)/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System. Inorganic Chemistry, 48(24), 11909-11920. https://doi.org/10.1021/ic902155m

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title = "Activation of the C-H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)(2+)/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System",

abstract = "We have investigated the reaction mechanism of the selective aerobic oxidation of primary alcohols into aldehydes using a bipy-copper complex and the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) radical as cocatalysts (Gamez et al. Chem. Commun. 2003, 2412-2415) and compared it to the well-known oxidation by the TEMPO",

author = "C. Michel and P. Belanzoni and P. Gamez and J. Reedijk and E.J. Baerends",

year = "2009",

doi = "10.1021/ic902155m",

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volume = "48",

pages = "11909--11920",

journal = "Inorganic Chemistry",

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Michel, C, Belanzoni, P, Gamez, P, Reedijk, J & Baerends, EJ 2009, 'Activation of the C-H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)(2+)/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System', Inorganic Chemistry, vol. 48, no. 24, pp. 11909-11920. https://doi.org/10.1021/ic902155m

Activation of the C-H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)(2+)/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System. / Michel, C.; Belanzoni, P.; Gamez, P. et al.
In: Inorganic Chemistry, Vol. 48, No. 24, 2009, p. 11909-11920.

Research output: Contribution to Journal › Article › Academic › peer-review

TY - JOUR

T1 - Activation of the C-H Bond by Electrophilic Attack: Theoretical Study of the Reaction Mechanism of the Aerobic Oxidation of Alcohols to Aldehydes by the Cu(bipy)(2+)/2,2,6,6-Tetramethylpiperidinyl-1-oxy Cocatalyst System

AU - Michel, C.

AU - Belanzoni, P.

AU - Gamez, P.

AU - Reedijk, J.

AU - Baerends, E.J.

PY - 2009

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N2 - We have investigated the reaction mechanism of the selective aerobic oxidation of primary alcohols into aldehydes using a bipy-copper complex and the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) radical as cocatalysts (Gamez et al. Chem. Commun. 2003, 2412-2415) and compared it to the well-known oxidation by the TEMPO

AB - We have investigated the reaction mechanism of the selective aerobic oxidation of primary alcohols into aldehydes using a bipy-copper complex and the 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) radical as cocatalysts (Gamez et al. Chem. Commun. 2003, 2412-2415) and compared it to the well-known oxidation by the TEMPO

U2 - 10.1021/ic902155m

DO - 10.1021/ic902155m

M3 - Article

SN - 0020-1669

VL - 48

SP - 11909

EP - 11920

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -