Analysis of parity violation in chiral molecules

R. Bast; A. Koers; A.S.P. Gomes; M. Illias; L. Visscher; P. Schwerdtfeger; T. Saue

doi:10.1039/c0cp01483d

Analysis of parity violation in chiral molecules

R. Bast, A. Koers, A.S.P. Gomes, M. Illias, L. Visscher, P. Schwerdtfeger, T. Saue

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

In order to guide the experimental search for parity violation in molecular systems, in part motivated by the possible link to biomolecular homochirality, we present a detailed analysis in a relativistic framework of the mechanism behind the tiny energy difference between enantiomers induced by the weak force. A decomposition of the molecular expectation value into atomic contributions reveals that the effect can be thought of as arising from a specific mixing of valence s

Original language	English
Pages (from-to)	864
Journal	Physical Chemistry Chemical Physics - PCCP
Volume	13
DOIs	https://doi.org/10.1039/c0cp01483d
Publication status	Published - 2011

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/c0cp01483d

Persistent URL (handle)

Copy link address

Cite this

@article{2fa618fee9734c8ca00faabb00759662,

title = "Analysis of parity violation in chiral molecules",

abstract = "In order to guide the experimental search for parity violation in molecular systems, in part motivated by the possible link to biomolecular homochirality, we present a detailed analysis in a relativistic framework of the mechanism behind the tiny energy difference between enantiomers induced by the weak force. A decomposition of the molecular expectation value into atomic contributions reveals that the effect can be thought of as arising from a specific mixing of valence s",

author = "R. Bast and A. Koers and A.S.P. Gomes and M. Illias and L. Visscher and P. Schwerdtfeger and T. Saue",

year = "2011",

doi = "10.1039/c0cp01483d",

language = "English",

volume = "13",

pages = "864",

journal = "Physical Chemistry Chemical Physics - PCCP",

issn = "1463-9076",

publisher = "The Royal Society of Chemistry",

}

TY - JOUR

T1 - Analysis of parity violation in chiral molecules

AU - Bast, R.

AU - Koers, A.

AU - Gomes, A.S.P.

AU - Illias, M.

AU - Visscher, L.

AU - Schwerdtfeger, P.

AU - Saue, T.

PY - 2011

Y1 - 2011

N2 - In order to guide the experimental search for parity violation in molecular systems, in part motivated by the possible link to biomolecular homochirality, we present a detailed analysis in a relativistic framework of the mechanism behind the tiny energy difference between enantiomers induced by the weak force. A decomposition of the molecular expectation value into atomic contributions reveals that the effect can be thought of as arising from a specific mixing of valence s

AB - In order to guide the experimental search for parity violation in molecular systems, in part motivated by the possible link to biomolecular homochirality, we present a detailed analysis in a relativistic framework of the mechanism behind the tiny energy difference between enantiomers induced by the weak force. A decomposition of the molecular expectation value into atomic contributions reveals that the effect can be thought of as arising from a specific mixing of valence s

U2 - 10.1039/c0cp01483d

DO - 10.1039/c0cp01483d

M3 - Article

SN - 1463-9076

VL - 13

SP - 864

JO - Physical Chemistry Chemical Physics - PCCP

JF - Physical Chemistry Chemical Physics - PCCP

ER -

Analysis of parity violation in chiral molecules

Abstract

UN SDGs

Access to Document

Persistent URL (handle)

Fingerprint

Cite this