Carbanions as Intermediates in the Formation of Grignard Reagents

G.P.M. van Klink; H.J.R. de Boer; G. Schat; O.S. Akkerman; F. Bickelhaupt; A.L. Spek

doi:10.1021/om011083a

Carbanions as Intermediates in the Formation of Grignard Reagents

G.P.M. van Klink, H.J.R. de Boer, G. Schat, O.S. Akkerman, F. Bickelhaupt, A.L. Spek

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.

Original language	English
Pages (from-to)	2119-2135
Number of pages	16
Journal	Organometallics
Volume	21
DOIs	https://doi.org/10.1021/om011083a
Publication status	Published - 2002

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1021/om011083a

Persistent URL (handle)

Persistent link

Cite this

@article{30e1cf95d9444ddea241310c75028626,

title = "Carbanions as Intermediates in the Formation of Grignard Reagents",

abstract = "The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.",

author = "\{van Klink\}, G.P.M. and \{de Boer\}, H.J.R. and G. Schat and O.S. Akkerman and F. Bickelhaupt and A.L. Spek",

year = "2002",

doi = "10.1021/om011083a",

language = "English",

volume = "21",

pages = "2119--2135",

journal = "Organometallics",

issn = "1520-6041",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Carbanions as Intermediates in the Formation of Grignard Reagents

AU - van Klink, G.P.M.

AU - de Boer, H.J.R.

AU - Schat, G.

AU - Akkerman, O.S.

AU - Bickelhaupt, F.

AU - Spek, A.L.

PY - 2002

Y1 - 2002

N2 - The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.

AB - The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.

UR - https://www.scopus.com/pages/publications/0038729573

UR - https://www.scopus.com/inward/citedby.url?scp=0038729573&partnerID=8YFLogxK

U2 - 10.1021/om011083a

DO - 10.1021/om011083a

M3 - Article

SN - 1520-6041

VL - 21

SP - 2119

EP - 2135

JO - Organometallics

JF - Organometallics

ER -

Carbanions as Intermediates in the Formation of Grignard Reagents

Abstract

UN SDGs

Access to Document

Persistent URL (handle)

Other files and links

Fingerprint

CCDC 114259: Experimental Crystal Structure Determination

Cite this

Carbanions as Intermediates in the Formation of Grignard Reagents

Abstract

UN SDGs

Access to Document

Persistent URL (handle)

Other files and links

Fingerprint

Datasets

CCDC 114259: Experimental Crystal Structure Determination

Cite this