Carbanions as Intermediates in the Formation of Grignard Reagents

G.P.M. van Klink; H.J.R. de Boer; G. Schat; O.S. Akkerman; F. Bickelhaupt; A.L. Spek

doi:10.1021/om011083a

Carbanions as Intermediates in the Formation of Grignard Reagents

G.P.M. van Klink
, H.J.R. de Boer
, G. Schat
, O.S. Akkerman
, F. Bickelhaupt
, A.L. Spek

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.

Original language	English
Pages (from-to)	2119-2135
Number of pages	16
Journal	Organometallics
Volume	21
DOIs	https://doi.org/10.1021/om011083a
Publication status	Published - 2002

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CCDC 114259: Experimental Crystal Structure Determination
Van Klink, G. P. M. (Contributor), De Boer, H. J. R. (Contributor), Schat, G. (Contributor), Akkerman, O. S. (Contributor), Bickelhaupt, F. (Contributor) & Spek, A. L. (Contributor), Unknown, 1 Jan 2002
DOI: 10.5517/cc3twsk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc3twsk&sid=DataCite
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title = "Carbanions as Intermediates in the Formation of Grignard Reagents",

abstract = "The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.",

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year = "2002",

doi = "10.1021/om011083a",

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AU - van Klink, G.P.M.

AU - de Boer, H.J.R.

AU - Schat, G.

AU - Akkerman, O.S.

AU - Bickelhaupt, F.

AU - Spek, A.L.

PY - 2002

Y1 - 2002

N2 - The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.

AB - The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.

U2 - 10.1021/om011083a

DO - 10.1021/om011083a

M3 - Article

SN - 1520-6041

VL - 21

SP - 2119

EP - 2135

JO - Organometallics

JF - Organometallics

ER -

Carbanions as Intermediates in the Formation of Grignard Reagents

Abstract

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CCDC 114259: Experimental Crystal Structure Determination

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