Cavity-ring-down spectroscopy on the b(1)Sigma(+)(g)-X-3 Sigma(-)(g) (1,0) band of oxygen isotopomers

H. Naus, S.J. van der Wiel, W.M.G. Ubachs

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Abstract

The b(1)Sigma(g)(+)-X(3)Sigma(g)(-) band of (OO)-O-16-O-17, (OO)-O-16-O-18, O-18(2), (OO)-O-17-O-18, and O-17(2) isotopomers was investigated employing the technique of cavity-ring-down spectroscopy. More than 400 transition frequencies of magnetic dipole lines were determined with a typical uncertainty of 0.01 cm(-1). This work results in new or improved accurate molecular constants for the excited b(1)Sigma(g)(+), upsilon = 1 state of all isotopomers and for the X(3)Sigma(g)(-), upsilon = 0 ground state of O-17(2). (C) 1998 Academic Press.
Original languageEnglish
Pages (from-to)162-168
JournalJournal of Molecular Spectroscopy
Volume192
Issue number1
DOIs
Publication statusPublished - 1998

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