C(CN)5–: Transition State or Intermediate?

F.M. Bickelhaupt; C. Fonseca Guerra; N.S. Zefirov

doi:10.1016/j.mencom.2010.03.002

C(CN)5–: Transition State or Intermediate?

F.M. Bickelhaupt, C. Fonseca Guerra, N.S. Zefirov

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Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Cyanide reacts with tetracyanomethane towards the tricyanomethyl anion via cyanophilic substitution; this is suggested by nitrogen isotope-labeling experiments and proven by density functional calculations at OLYP/TZ2P. © 2010.

Original language	English
Pages (from-to)	72-73
Journal	Mendeleev Communications
Issue number	20
DOIs	https://doi.org/10.1016/j.mencom.2010.03.002
Publication status	Published - 2010

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.mencom.2010.03.002

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Cite this

@article{23a8b8fb11e04a1093bc870dbb413290,

title = "C(CN)5–: Transition State or Intermediate?",

abstract = "Cyanide reacts with tetracyanomethane towards the tricyanomethyl anion via cyanophilic substitution; this is suggested by nitrogen isotope-labeling experiments and proven by density functional calculations at OLYP/TZ2P. {\textcopyright} 2010.",

author = "F.M. Bickelhaupt and \{Fonseca Guerra\}, C. and N.S. Zefirov",

year = "2010",

doi = "10.1016/j.mencom.2010.03.002",

language = "English",

pages = "72--73",

journal = "Mendeleev Communications",

issn = "0959-9436",