Chl-a triplet quenching by peridinin in H-PCP and organic solvent revealed by step-scan FTIR time-resolved spectroscopy

C. Bonetti, M.T.A. Alexandre, R.G. Hiller, J.T.M. Kennis, R. van Grondelle

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Triplet-state dynamics in Chl-a/Per mixtures in organic solvent and in native H-PCP were studied by means of step-scan FTIR spectroscopy. A single decay component of 10 μs was observed for the H-PCP triplet, the spectrum of which closely matches the 13 μs component of A-PCP [Alexandre et al., Biophysical Journal 93 (2007) 2118-2128], implying that in H-PCP, as in A-PCP, the peridinin triplet state is shared with Chl-a. In a mixture of Chl-a and Per in THF, TEET from
Original languageEnglish
Pages (from-to)63-69
JournalChemical Physics
Volume357
Issue number1-3
DOIs
Publication statusPublished - 2009

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