Chlorinated paraffins and tris (1-chloro-2-propyl) phosphate in spray polyurethane foams – A source for indoor exposure?

In this study, we investigated chemical additives present in new and used spray polyurethane foams (SPFs) and assessed the dermal transfer through direct contact. This first study shows that cured do-it-yourself spray one-component SPFs (OCFs) often contain chlorinated paraffins (C₁₄-C₃₇), and tris (1-chloro-2-propyl) phosphate (TCIPP), ranging 0.2–50%, and 0.9–30% w/w, respectively. Six OCFs contained CP levels ranging 22–50% w/w, whereas nine OCFs used for similar applications only contained CP levels ranging 2–17% w/w. It is unclear if the combination CPs/TCIPP is meant to improve the flame retardancy of products, and could suggest an unnecessary use of high CPs/TCIPP concentrations in OCFs. The two-component SPFs (TCFs) contained only TCIPP with levels ranging from 7.0% to 9.0%. The CPs and TCIPP were easily transferred from cured OCFs to the hands. Levels up to 590 µg per hand for CPs and up to 2.7 µg per hand for TCIPP were found. After end-of-life, it is challenging to recycle used SPFs. They may, therefore, end up at landfills where the TCIPP/CPs may leach into the environment. Therefore, further investigation is needed to assess potential exposure risks associated with general and occupational use, and the impact of landfill leaching on the environment.