Dibenzo[b,f]phosphepines – Novel phosphane-olefin ligands for transition metals

V. Lyaskovskyy; R.J.A. Moes; S. Burck; W.I. Dzik; M. Lutz; A.W. Ehlers; B. de Bruin; K. Lammertsma

doi:10.1021/om301012z

Dibenzo[b,f]phosphepines – Novel phosphane-olefin ligands for transition metals

V. Lyaskovskyy, R.J.A. Moes, S. Burck, W.I. Dzik, M. Lutz, A.W. Ehlers, B. de Bruin, K. Lammertsma

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

New, stable heterobidentate phosphane-olefin ligands based on the dibenzo[b,f]phosphepine backbone are reported together with their redox properties and coordination chemistry to rhodium(I). The X-ray crystal structures and DFT calculations show different conformations for the P-phenyl (6a) and P-mesityl (6b) derivatives. Cyclic voltammetry (vs Fc/Fc

Original language	English
Pages (from-to)	363-373
Journal	Organometallics
Volume	32
DOIs	https://doi.org/10.1021/om301012z
Publication status	Published - 2013

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CCDC 945993: Experimental Crystal Structure Determination
Lyaskovskyy, V. (Contributor), Van Dijk-Moes, R. J. A. (Contributor), Burck, S. (Contributor), Dzik, W. I. (Contributor), Lutz, M. (Contributor), Ehlers, A. W. (Contributor), Slootweg, C. (Contributor), De Bruin, B. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 28 Jan 2013
DOI: 10.5517/cc10rcx1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10rcx1&sid=DataCite
Dataset
CCDC 945992: Experimental Crystal Structure Determination
Lyaskovskyy, V. (Contributor), Van Dijk-Moes, R. J. A. (Contributor), Burck, S. (Contributor), Dzik, W. I. (Contributor), Lutz, M. (Contributor), Ehlers, A. W. (Contributor), Slootweg, C. (Contributor), De Bruin, B. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 28 Jan 2013
DOI: 10.5517/cc10rcw0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10rcw0&sid=DataCite
Dataset
CCDC 945989: Experimental Crystal Structure Determination
Lyaskovskyy, V. (Contributor), Van Dijk-Moes, R. J. A. (Contributor), Burck, S. (Contributor), Dzik, W. I. (Contributor), Lutz, M. (Contributor), Ehlers, A. W. (Contributor), Slootweg, C. (Contributor), De Bruin, B. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 28 Jan 2013
DOI: 10.5517/cc10rcsx, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10rcsx&sid=DataCite
Dataset

Cite this

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title = "Dibenzo[b,f]phosphepines – Novel phosphane-olefin ligands for transition metals",

abstract = "New, stable heterobidentate phosphane-olefin ligands based on the dibenzo[b,f]phosphepine backbone are reported together with their redox properties and coordination chemistry to rhodium(I). The X-ray crystal structures and DFT calculations show different conformations for the P-phenyl (6a) and P-mesityl (6b) derivatives. Cyclic voltammetry (vs Fc/Fc",

author = "V. Lyaskovskyy and R.J.A. Moes and S. Burck and W.I. Dzik and M. Lutz and A.W. Ehlers and {de Bruin}, B. and K. Lammertsma",

year = "2013",

doi = "10.1021/om301012z",

language = "English",

volume = "32",

pages = "363--373",

journal = "Organometallics",

issn = "1520-6041",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Dibenzo[b,f]phosphepines – Novel phosphane-olefin ligands for transition metals

AU - Lyaskovskyy, V.

AU - Moes, R.J.A.

AU - Burck, S.

AU - Dzik, W.I.

AU - Lutz, M.

AU - Ehlers, A.W.

AU - de Bruin, B.

AU - Lammertsma, K.

PY - 2013

Y1 - 2013

N2 - New, stable heterobidentate phosphane-olefin ligands based on the dibenzo[b,f]phosphepine backbone are reported together with their redox properties and coordination chemistry to rhodium(I). The X-ray crystal structures and DFT calculations show different conformations for the P-phenyl (6a) and P-mesityl (6b) derivatives. Cyclic voltammetry (vs Fc/Fc

AB - New, stable heterobidentate phosphane-olefin ligands based on the dibenzo[b,f]phosphepine backbone are reported together with their redox properties and coordination chemistry to rhodium(I). The X-ray crystal structures and DFT calculations show different conformations for the P-phenyl (6a) and P-mesityl (6b) derivatives. Cyclic voltammetry (vs Fc/Fc

U2 - 10.1021/om301012z

DO - 10.1021/om301012z

M3 - Article

VL - 32

SP - 363

EP - 373

JO - Organometallics

JF - Organometallics

SN - 1520-6041

ER -

Dibenzo[b,f]phosphepines – Novel phosphane-olefin ligands for transition metals

Abstract

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Datasets

CCDC 945993: Experimental Crystal Structure Determination

CCDC 945992: Experimental Crystal Structure Determination

CCDC 945989: Experimental Crystal Structure Determination

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