Dibenzo[b,f]phosphepines – Novel phosphane-olefin ligands for transition metals

V. Lyaskovskyy, R.J.A. Moes, S. Burck, W.I. Dzik, M. Lutz, A.W. Ehlers, B. de Bruin, K. Lammertsma

Research output: Contribution to JournalArticleAcademicpeer-review


New, stable heterobidentate phosphane-olefin ligands based on the dibenzo[b,f]phosphepine backbone are reported together with their redox properties and coordination chemistry to rhodium(I). The X-ray crystal structures and DFT calculations show different conformations for the P-phenyl (6a) and P-mesityl (6b) derivatives. Cyclic voltammetry (vs Fc/Fc
Original languageEnglish
Pages (from-to)363-373
Publication statusPublished - 2013


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