Differential cross sections for collisions of hexapole state-selected NO with He

A. Gijsbertsen, H.V.J. Linnartz, G. Rus, A.E. Wiskerke, S. Stolte, D.W. Chandler, J. Klos

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Abstract

The first measurements of differential inelastic collision cross sections of fully state-selected NO (j=12, Ω- =12, ε=-1) with He are presented. Full state selection is achieved by a 2 m long hexapole, which allows for a systematic study of the effect of parity conservation and breaking on the differential cross section. The collisionally excited NO molecules are detected using a resonant (1+ 1′) REMPI ionization scheme in combination with the velocity-mapped, ion-imaging technique. The current experimental configuration minimizes the contribution of noncolliding NO molecules in other rotational states j, Ω-, ε -that contaminates images- and allows for study of the collision process at an unprecedented level of detail. A simple method to correct ion images for collision-induced alignment is presented as well and its performance is demonstrated. The present results show a significant difference between differential cross sections for scattering into the upper and lower component of the Λ -doublet of NO. This result cannot be due to the energy splitting between these components. © 2005 American Institute of Physics.
Original languageEnglish
Pages (from-to)224305
JournalJournal of Chemical Physics
Volume123
DOIs
Publication statusPublished - 2005

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