Double layer formation in Mg-TM switchable mirrors (TM : Ni, Co, Fe)

W. Lohstroh; R.J. Westerwaal; A.C. Lokhorst; J.L.M. van Mechelen; B. Dam; R.P. Griessen

doi:10.1016/j.jallcom.2004.11.127

Double layer formation in Mg-TM switchable mirrors (TM : Ni, Co, Fe)

W. Lohstroh, R.J. Westerwaal, A.C. Lokhorst, J.L.M. van Mechelen, B. Dam, R.P. Griessen

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

The optical properties of Mg-TM (TM: Ni, Co, Fe; Mg:TM ≈ 2) thin films during hydrogenation are investigated using reflection and transmission measurements. Mg-Ni and Mg-Co show an unusual behavior upon exposure to hydrogen. The nucleation of the hydride starts at the film substrate interface and not - as intuitively expected - at the Pd covered top side of the film. Consequently, a double layer structure is formed. Reflection measurements are used to identify the loading behavior as the double layering yields to an remarkable optical black state at intermediate hydrogen concentrations. Photometric measurements on samples loaded at H

Original language	English
Pages (from-to)	490-493
Journal	Journal of Alloys and Compounds
Volume	404-406
DOIs	https://doi.org/10.1016/j.jallcom.2004.11.127
Publication status	Published - 2005

Bibliographical note

Times Cited: 8 9th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications SEP 05-10, 2004 AGH Univ Sci & Technol, Fac Phys & Comp Sci, Cracow, POLAND

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@article{466c51645424443497325582ef935271,

title = "Double layer formation in Mg-TM switchable mirrors (TM : Ni, Co, Fe)",

abstract = "The optical properties of Mg-TM (TM: Ni, Co, Fe; Mg:TM ≈ 2) thin films during hydrogenation are investigated using reflection and transmission measurements. Mg-Ni and Mg-Co show an unusual behavior upon exposure to hydrogen. The nucleation of the hydride starts at the film substrate interface and not - as intuitively expected - at the Pd covered top side of the film. Consequently, a double layer structure is formed. Reflection measurements are used to identify the loading behavior as the double layering yields to an remarkable optical black state at intermediate hydrogen concentrations. Photometric measurements on samples loaded at H",

author = "W. Lohstroh and R.J. Westerwaal and A.C. Lokhorst and {van Mechelen}, J.L.M. and B. Dam and R.P. Griessen",

note = "Times Cited: 8 9th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications SEP 05-10, 2004 AGH Univ Sci & Technol, Fac Phys & Comp Sci, Cracow, POLAND",

year = "2005",

doi = "10.1016/j.jallcom.2004.11.127",

language = "English",

volume = "404-406",

pages = "490--493",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Double layer formation in Mg-TM switchable mirrors (TM : Ni, Co, Fe)

AU - Lohstroh, W.

AU - Westerwaal, R.J.

AU - Lokhorst, A.C.

AU - van Mechelen, J.L.M.

AU - Dam, B.

AU - Griessen, R.P.

N1 - Times Cited: 8 9th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications SEP 05-10, 2004 AGH Univ Sci & Technol, Fac Phys & Comp Sci, Cracow, POLAND

PY - 2005

Y1 - 2005

N2 - The optical properties of Mg-TM (TM: Ni, Co, Fe; Mg:TM ≈ 2) thin films during hydrogenation are investigated using reflection and transmission measurements. Mg-Ni and Mg-Co show an unusual behavior upon exposure to hydrogen. The nucleation of the hydride starts at the film substrate interface and not - as intuitively expected - at the Pd covered top side of the film. Consequently, a double layer structure is formed. Reflection measurements are used to identify the loading behavior as the double layering yields to an remarkable optical black state at intermediate hydrogen concentrations. Photometric measurements on samples loaded at H

AB - The optical properties of Mg-TM (TM: Ni, Co, Fe; Mg:TM ≈ 2) thin films during hydrogenation are investigated using reflection and transmission measurements. Mg-Ni and Mg-Co show an unusual behavior upon exposure to hydrogen. The nucleation of the hydride starts at the film substrate interface and not - as intuitively expected - at the Pd covered top side of the film. Consequently, a double layer structure is formed. Reflection measurements are used to identify the loading behavior as the double layering yields to an remarkable optical black state at intermediate hydrogen concentrations. Photometric measurements on samples loaded at H

U2 - 10.1016/j.jallcom.2004.11.127

DO - 10.1016/j.jallcom.2004.11.127

M3 - Article

SN - 0925-8388

VL - 404-406

SP - 490

EP - 493

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Double layer formation in Mg-TM switchable mirrors (TM : Ni, Co, Fe)

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