Enantioselective femtosecond laser photoionization spectrometry of limonene using photoelectron circular dichroism

M.M. Rafiee Fanood, M.H.M. Janssen, I. Powis

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Limonene is ionized by circularly polarized 420 nm femtosecond laser pulses. Ion mass and photoelectron energy spectra identify the dominant (2 + 1) multiphoton ionization mechanism, aided by TDDFT calculations of the Rydberg excitations. Photoelectron circular dichroism measurements on pure enantiomers reveal a chiral asymmetry of ±4 %. This journal is
Original languageEnglish
Pages (from-to)8614-8617
JournalPhysical Chemistry Chemical Physics - PCCP
Volume17
Issue number14
DOIs
Publication statusPublished - 2015

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