Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas

R. Berera; I.H.M. van Stokkum; G. Kodis; A.E. Keirstead; S. Pillai; C. Herrero; R.E. Palacios; M. Vengris; R. van Grondelle; D. Gust; T.A. Moore; A.L. Moore; J.T.M. Kennis

doi:10.1021/jp071010q

Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas

R. Berera, I.H.M. van Stokkum, G. Kodis, A.E. Keirstead, S. Pillai, C. Herrero, R.E. Palacios, M. Vengris, R. van Grondelle, D. Gust, T.A. Moore, A.L. Moore, J.T.M. Kennis

Biophysics Photosynthesis/Energy

Research output: Contribution to Journal › Article › Academic › peer-review

320 Downloads (Pure)

Abstract

We present results from transient absorption spectroscopy on a series of artificial light-harvesting dyads made up of a zinc phthalocyanine (Pc) covalently linked to carotenoids with 9, 10, or 11 conjugated carbon-carbon double bonds, referred to as dyads 1, 2, and 3, respectively. We assessed the energy transfer and excited-state deactivation pathways following excitation of the strongly allowed carotenoid 82 state as a function of the conjugation length. The 82 state rapidly relaxes to the S* and Si states. In all systems we detected a new pathway of energy deactivation within the carotenoid manifold in which the S* state acts as an intermediate state in the 8

Original language	English
Pages (from-to)	6868-6877
Journal	Journal of Physical Chemistry B
Volume	111
Issue number	24
DOIs	https://doi.org/10.1021/jp071010q
Publication status	Published - 2007

Bibliographical note

Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1021/jp071010q

225589Final published version, 371 KB

Persistent URL (handle)

Copy link address

Cite this

Berera, R., van Stokkum, I. H. M., Kodis, G., Keirstead, A. E., Pillai, S., Herrero, C., Palacios, R. E., Vengris, M., van Grondelle, R., Gust, D., Moore, T. A., Moore, A. L., & Kennis, J. T. M. (2007). Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas. Journal of Physical Chemistry B, 111(24), 6868-6877. https://doi.org/10.1021/jp071010q

@article{010ffddebfdb452fb756702f28194cc0,

title = "Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas",

abstract = "We present results from transient absorption spectroscopy on a series of artificial light-harvesting dyads made up of a zinc phthalocyanine (Pc) covalently linked to carotenoids with 9, 10, or 11 conjugated carbon-carbon double bonds, referred to as dyads 1, 2, and 3, respectively. We assessed the energy transfer and excited-state deactivation pathways following excitation of the strongly allowed carotenoid 82 state as a function of the conjugation length. The 82 state rapidly relaxes to the S* and Si states. In all systems we detected a new pathway of energy deactivation within the carotenoid manifold in which the S* state acts as an intermediate state in the 8",

author = "R. Berera and {van Stokkum}, I.H.M. and G. Kodis and A.E. Keirstead and S. Pillai and C. Herrero and R.E. Palacios and M. Vengris and {van Grondelle}, R. and D. Gust and T.A. Moore and A.L. Moore and J.T.M. Kennis",

note = "Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas",

year = "2007",

doi = "10.1021/jp071010q",

language = "English",

volume = "111",

pages = "6868--6877",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

publisher = "American Chemical Society",

number = "24",

}

Berera, R, van Stokkum, IHM, Kodis, G, Keirstead, AE, Pillai, S, Herrero, C, Palacios, RE, Vengris, M, van Grondelle, R, Gust, D, Moore, TA, Moore, AL & Kennis, JTM 2007, 'Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas', Journal of Physical Chemistry B, vol. 111, no. 24, pp. 6868-6877. https://doi.org/10.1021/jp071010q

TY - JOUR

T1 - Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas

AU - Berera, R.

AU - van Stokkum, I.H.M.

AU - Kodis, G.

AU - Keirstead, A.E.

AU - Pillai, S.

AU - Herrero, C.

AU - Palacios, R.E.

AU - Vengris, M.

AU - van Grondelle, R.

AU - Gust, D.

AU - Moore, T.A.

AU - Moore, A.L.

AU - Kennis, J.T.M.

N1 - Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas

PY - 2007

Y1 - 2007

N2 - We present results from transient absorption spectroscopy on a series of artificial light-harvesting dyads made up of a zinc phthalocyanine (Pc) covalently linked to carotenoids with 9, 10, or 11 conjugated carbon-carbon double bonds, referred to as dyads 1, 2, and 3, respectively. We assessed the energy transfer and excited-state deactivation pathways following excitation of the strongly allowed carotenoid 82 state as a function of the conjugation length. The 82 state rapidly relaxes to the S* and Si states. In all systems we detected a new pathway of energy deactivation within the carotenoid manifold in which the S* state acts as an intermediate state in the 8

AB - We present results from transient absorption spectroscopy on a series of artificial light-harvesting dyads made up of a zinc phthalocyanine (Pc) covalently linked to carotenoids with 9, 10, or 11 conjugated carbon-carbon double bonds, referred to as dyads 1, 2, and 3, respectively. We assessed the energy transfer and excited-state deactivation pathways following excitation of the strongly allowed carotenoid 82 state as a function of the conjugation length. The 82 state rapidly relaxes to the S* and Si states. In all systems we detected a new pathway of energy deactivation within the carotenoid manifold in which the S* state acts as an intermediate state in the 8

U2 - 10.1021/jp071010q

DO - 10.1021/jp071010q

M3 - Article

SN - 1520-6106

VL - 111

SP - 6868

EP - 6877

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 24

ER -

Energy transfer, excited-state deactivation, and exciplex formation in artificial caroteno-phthalocyanine light-harvesting antennas

Abstract

Bibliographical note

UN SDGs

Access to Document

Persistent URL (handle)

Fingerprint

Cite this