Enlightening developments in 1,3-P,N-ligand-stabilized multinuclear complexes: A shift from catalysis to photoluminescence

Mark K. Rong; Flip Holtrop; J. Chris Slootweg; Koop Lammertsma

doi:10.1016/j.ccr.2018.11.012

Enlightening developments in 1,3-P,N-ligand-stabilized multinuclear complexes: A shift from catalysis to photoluminescence

Mark K. Rong, Flip Holtrop, J. Chris Slootweg, Koop Lammertsma^*

^*Corresponding author for this work

Research output: Contribution to Journal › Review article › Academic › peer-review

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Abstract

1,3-P,N-ligands provide the ideal spatial separation to facilitate homo and hetero metal-metal interactions to access multinuclear complexes. The rich chemistry of such complexes includes applications in coordination chemistry, metal-activation and (cooperative) catalysis. However, it has been especially the fruitful combination in photoluminescent P,N-coinage metal complexes which has renewed interest in these ligands. While the field classically focused on dinuclear species, now also coinage metal clusters have been studied for use in catalysis and photophysical applications. Reviewed are recent developments from 2009 to mid-2017.

Original language	English
Pages (from-to)	57-68
Number of pages	12
Journal	Coordination Chemistry Reviews
Volume	382
Early online date	27 Dec 2018
DOIs	https://doi.org/10.1016/j.ccr.2018.11.012
Publication status	Published - 1 Mar 2019

Funding

This work was supported by the Council for Chemical Sciences of the Netherlands Organization for Scientific Research (NWO/CW).

Funders	Funder number
NWO/CW
Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Keywords

Coinage metal clusters
Homogeneous catalysis
Metal-metal bonds
P,N-ligands
Photoluminescence
Transition metal complexes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.ccr.2018.11.012

Enlightening developments in 1,3-P,N-ligand-stabilized multinuclear complexesFinal published version, 2.01 MBLicence: Article 25fa Dutch Copyright Act

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title = "Enlightening developments in 1,3-P,N-ligand-stabilized multinuclear complexes: A shift from catalysis to photoluminescence",

abstract = "1,3-P,N-ligands provide the ideal spatial separation to facilitate homo and hetero metal-metal interactions to access multinuclear complexes. The rich chemistry of such complexes includes applications in coordination chemistry, metal-activation and (cooperative) catalysis. However, it has been especially the fruitful combination in photoluminescent P,N-coinage metal complexes which has renewed interest in these ligands. While the field classically focused on dinuclear species, now also coinage metal clusters have been studied for use in catalysis and photophysical applications. Reviewed are recent developments from 2009 to mid-2017.",

keywords = "Coinage metal clusters, Homogeneous catalysis, Metal-metal bonds, P,N-ligands, Photoluminescence, Transition metal complexes",

author = "Rong, {Mark K.} and Flip Holtrop and Slootweg, {J. Chris} and Koop Lammertsma",

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T2 - A shift from catalysis to photoluminescence

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AU - Holtrop, Flip

AU - Slootweg, J. Chris

AU - Lammertsma, Koop

PY - 2019/3/1

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N2 - 1,3-P,N-ligands provide the ideal spatial separation to facilitate homo and hetero metal-metal interactions to access multinuclear complexes. The rich chemistry of such complexes includes applications in coordination chemistry, metal-activation and (cooperative) catalysis. However, it has been especially the fruitful combination in photoluminescent P,N-coinage metal complexes which has renewed interest in these ligands. While the field classically focused on dinuclear species, now also coinage metal clusters have been studied for use in catalysis and photophysical applications. Reviewed are recent developments from 2009 to mid-2017.

AB - 1,3-P,N-ligands provide the ideal spatial separation to facilitate homo and hetero metal-metal interactions to access multinuclear complexes. The rich chemistry of such complexes includes applications in coordination chemistry, metal-activation and (cooperative) catalysis. However, it has been especially the fruitful combination in photoluminescent P,N-coinage metal complexes which has renewed interest in these ligands. While the field classically focused on dinuclear species, now also coinage metal clusters have been studied for use in catalysis and photophysical applications. Reviewed are recent developments from 2009 to mid-2017.

KW - Coinage metal clusters

KW - Homogeneous catalysis

KW - Metal-metal bonds

KW - P,N-ligands

KW - Photoluminescence

KW - Transition metal complexes

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Enlightening developments in 1,3-P,N-ligand-stabilized multinuclear complexes: A shift from catalysis to photoluminescence

Abstract

Funding

Keywords

UN SDGs

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