Geminal phosphorus/aluminum-based frustrated Lewis pairs: C-H versus C≡C activation and CO2 fixation

C. Appelt; H. Westenberg; F. Bertini; A.W. Ehlers; J.C. Slootweg; K. Lammertsma; W. Uhl

doi:10.1002/anie.201006901

Geminal phosphorus/aluminum-based frustrated Lewis pairs: C-H versus C≡C activation and CO2 fixation

C. Appelt, H. Westenberg, F. Bertini, A.W. Ehlers, J.C. Slootweg, K. Lammertsma, W. Uhl

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Catch it! Geminal phosphorus/aluminum-based frustrated Lewis pairs (FLPs) are easily obtained by hydroalumination of alkynylphosphines. These FLPs can activate terminal acetylenes by two competitive pathways, which were analyzed by DFT calculations, and they can bind carbon dioxide reversibly. Therefore, alongside polyfluorinated boranes, alanes are also ideal Lewis acids for FLP chemistry. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	3925-3928
Journal	Angewandte Chemie International Edition in English
Volume	50
DOIs	https://doi.org/10.1002/anie.201006901
Publication status	Published - 2011

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abstract = "Catch it! Geminal phosphorus/aluminum-based frustrated Lewis pairs (FLPs) are easily obtained by hydroalumination of alkynylphosphines. These FLPs can activate terminal acetylenes by two competitive pathways, which were analyzed by DFT calculations, and they can bind carbon dioxide reversibly. Therefore, alongside polyfluorinated boranes, alanes are also ideal Lewis acids for FLP chemistry. {\textcopyright} 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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AU - Appelt, C.

AU - Westenberg, H.

AU - Bertini, F.

AU - Ehlers, A.W.

AU - Slootweg, J.C.

AU - Lammertsma, K.

AU - Uhl, W.

PY - 2011

Y1 - 2011

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AB - Catch it! Geminal phosphorus/aluminum-based frustrated Lewis pairs (FLPs) are easily obtained by hydroalumination of alkynylphosphines. These FLPs can activate terminal acetylenes by two competitive pathways, which were analyzed by DFT calculations, and they can bind carbon dioxide reversibly. Therefore, alongside polyfluorinated boranes, alanes are also ideal Lewis acids for FLP chemistry. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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DO - 10.1002/anie.201006901

M3 - Article

SN - 0570-0833

VL - 50

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

ER -

Geminal phosphorus/aluminum-based frustrated Lewis pairs: C-H versus C≡C activation and CO2 fixation

Abstract

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