Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study

A.T. Termaten, T. Nijbacker, A.W. Ehlers, M. Schakel, M. Lutz, A.L Spek, M. McKee, K. Lammertsma

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

The properties of the 16-electron phosphinidene complex [CpRIr=PR] were investigated experimentally and theoretically. Density functional theory calculations show a preferred bent geometry for the model complex [CpIr=PH], in contrast to the linear structure of [CpIr=NH]. Dimerization to give [{CpIr=PH}
Original languageEnglish
Pages (from-to)4063-4072
JournalChemistry: A European Journal
Volume10
Issue number16
DOIs
Publication statusPublished - 2004

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