Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study

A.T. Termaten; T. Nijbacker; A.W. Ehlers; M. Schakel; M. Lutz; A.L Spek; M. McKee; K. Lammertsma

doi:10.1002/chem.200400080

Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study

A.T. Termaten, T. Nijbacker, A.W. Ehlers, M. Schakel, M. Lutz, A.L Spek, M. McKee, K. Lammertsma

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

The properties of the 16-electron phosphinidene complex [CpRIr=PR] were investigated experimentally and theoretically. Density functional theory calculations show a preferred bent geometry for the model complex [CpIr=PH], in contrast to the linear structure of [CpIr=NH]. Dimerization to give [{CpIr=PH}

Original language	English
Pages (from-to)	4063-4072
Journal	Chemistry: A European Journal
Volume	10
Issue number	16
DOIs	https://doi.org/10.1002/chem.200400080
Publication status	Published - 2004

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10.1002/chem.200400080

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CCDC 229360: Experimental Crystal Structure Determination
Termaten, A. T. (Contributor), Nijbacker, T. (Contributor), Ehlers, A. W. (Contributor), Schakel, M. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor), McKee, M. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2005
DOI: 10.5517/cc7pnq8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7pnq8&sid=DataCite
Dataset / Software: Dataset
CCDC 229359: Experimental Crystal Structure Determination
Termaten, A. T. (Contributor), Nijbacker, T. (Contributor), Ehlers, A. W. (Contributor), Schakel, M. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor), McKee, M. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2005
DOI: 10.5517/cc7pnp7, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7pnp7&sid=DataCite
Dataset / Software: Dataset

Cite this

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title = "Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study",

abstract = "The properties of the 16-electron phosphinidene complex [CpRIr=PR] were investigated experimentally and theoretically. Density functional theory calculations show a preferred bent geometry for the model complex [CpIr=PH], in contrast to the linear structure of [CpIr=NH]. Dimerization to give [{CpIr=PH}",

author = "A.T. Termaten and T. Nijbacker and A.W. Ehlers and M. Schakel and M. Lutz and A.L Spek and M. McKee and K. Lammertsma",

year = "2004",

doi = "10.1002/chem.200400080",

language = "English",

volume = "10",

pages = "4063--4072",

journal = "Chemistry: A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc.",

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TY - JOUR

T1 - Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study

AU - Termaten, A.T.

AU - Nijbacker, T.

AU - Ehlers, A.W.

AU - Schakel, M.

AU - Lutz, M.

AU - Spek, A.L

AU - McKee, M.

AU - Lammertsma, K.

PY - 2004

Y1 - 2004

N2 - The properties of the 16-electron phosphinidene complex [CpRIr=PR] were investigated experimentally and theoretically. Density functional theory calculations show a preferred bent geometry for the model complex [CpIr=PH], in contrast to the linear structure of [CpIr=NH]. Dimerization to give [{CpIr=PH}

AB - The properties of the 16-electron phosphinidene complex [CpRIr=PR] were investigated experimentally and theoretically. Density functional theory calculations show a preferred bent geometry for the model complex [CpIr=PH], in contrast to the linear structure of [CpIr=NH]. Dimerization to give [{CpIr=PH}

U2 - 10.1002/chem.200400080

DO - 10.1002/chem.200400080

M3 - Article

SN - 0947-6539

VL - 10

SP - 4063

EP - 4072

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

IS - 16

ER -

Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study

Abstract

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CCDC 229360: Experimental Crystal Structure Determination

CCDC 229359: Experimental Crystal Structure Determination

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