Abstract
The properties of the 16-electron phosphinidene complex [CpRIr=PR] were investigated experimentally and theoretically. Density functional theory calculations show a preferred bent geometry for the model complex [CpIr=PH], in contrast to the linear structure of [CpIr=NH]. Dimerization to give [{CpIr=PH}
| Original language | English |
|---|---|
| Pages (from-to) | 4063-4072 |
| Journal | Chemistry: A European Journal |
| Volume | 10 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2004 |
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CCDC 229359: Experimental Crystal Structure Determination
Termaten, A. T. (Contributor), Nijbacker, T. (Contributor), Ehlers, A. W. (Contributor), Schakel, M. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor), McKee, M. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2005
DOI: 10.5517/cc7pnp7, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7pnp7&sid=DataCite
Dataset
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CCDC 229360: Experimental Crystal Structure Determination
Termaten, A. T. (Contributor), Nijbacker, T. (Contributor), Ehlers, A. W. (Contributor), Schakel, M. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor), McKee, M. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2005
DOI: 10.5517/cc7pnq8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7pnq8&sid=DataCite
Dataset