Geochemical characterization of the middle and late Pleistocene alluvial fan-dominated infill of the northern part of the Weihe Basin, Central China

Major reorganizations in climate and tectonic regime occurred in East Asia during the Pleistocene, resulting in large-scale environmental changes. In this paper a detailed geochemical and mineralogical record of these changes is presented from a distal alluvial fan sedimentary sequence in the northern Weihe Basin. We established that, in addition to glacial-interglacial variation, there are three distinctly different units deposited over the past 1 m.y. These units are the result of variations in the overall tectonic regime in the northern Weihe Basin. Fine-grained detrital minerals were predominantly delivered during colder climatic periods, whereas evaporative minerals were dominantly deposited during the warmer, interglacial periods, probably as a result of strong seasonal contrast. This compositional variation demonstrates the importance of climate control on hinterland erosion, surface runoff, chemical weathering and evaporation. Al-normalized ratios of indicative major elements relative to average loess composition, indicate important variations in sedimentary processes, mostly related to sediment flux. Si-enrichment is an index for past flooding events, while Fe enrichment, just like K and Ti, reflects influx of clays. In contrast, Ca and Mn are strongly enriched throughout the core, associated with the authigenic precipitation of carbonates, especially during interglacial periods. The lower (~ 1000–690 ka) and upper (~ 330–0 ka) units of the core are characterized by relative intense and frequent flooding, which coincided with extensive ponding in the study area. In the middle unit (~ 690–330 ka) increased salinity levels caused by evaporation, as reflected in the high Sr/Ca ratio and dolomite abundance, led to increased carbonate precipitation. Simultaneously, the increased influx of fine sediments indicates increased clay production in the source area as a result of a more intense summer monsoon strength after 600 ka.