Abstract
Controlling crystal growth and reducing the number of grain boundaries are crucial to maximize the charge carrier transport in organic-inorganic perovskite field-effect transistors (FETs). Herein, the crystallization and growth kinetics of a Sn(ii)-based 2D perovskite, using 2-thiopheneethylammonium (TEA) as the organic cation spacer, were effectively regulated by the hot-casting method. With increasing crystalline grain size, the local charge carrier mobility is found to increase moderately from 13 cm2 V−1 s−1 to 16 cm2 V−1 s−1, as inferred from terahertz (THz) spectroscopy. In contrast, the FET operation parameters, including mobility, threshold voltage, hysteresis, and subthreshold swing, improve substantially with larger grain size. The optimized 2D (TEA)2SnI4 transistor exhibits hole mobility of up to 0.34 cm2 V−1 s−1 at 295 K and a higher value of 1.8 cm2 V−1 s−1 at 100 K. Our work provides an important insight into the grain engineering of 2D perovskites for high-performance FETs.
Original language | English |
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Pages (from-to) | 2633-2643 |
Number of pages | 11 |
Journal | Materials Horizons |
Volume | 9 |
Issue number | 10 |
Early online date | 9 Aug 2022 |
DOIs | |
Publication status | Published - 1 Oct 2022 |
Bibliographical note
Funding Information:S. Wang thanks the China Scholarship Council (CSC, 201906890035) for financial support. M. Mandal acknowledges postdoctoral support from the Alexander von Humboldt Foundation. T. Marszalek acknowledges the Foundation for Polish Science financed by the European Union under the European Regional Development Fund (POIR.04.04.00-00-3ED8/17). The authors thank Dr Hao Wu for the help with UPS measurements. This work was supported by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) - project number 424708673 and by the KAUST Office of Sponsored Research (OSR). Open Access funding provided by the Max Planck Society.
Funding Information:
S. Wang thanks the China Scholarship Council (CSC, 201906890035) for financial support. M. Mandal acknowledges postdoctoral support from the Alexander von Humboldt Foundation. T. Marszalek acknowledges the Foundation for Polish Science financed by the European Union under the European Regional Development Fund (POIR.04.04.00-00-3ED8/17). The authors thank Dr Hao Wu for the help with UPS measurements. This work was supported by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – project number 424708673 and by the KAUST Office of Sponsored Research (OSR). Open Access funding provided by the Max Planck Society.
Publisher Copyright:
© 2022 The Royal Society of Chemistry.
Funding
S. Wang thanks the China Scholarship Council (CSC, 201906890035) for financial support. M. Mandal acknowledges postdoctoral support from the Alexander von Humboldt Foundation. T. Marszalek acknowledges the Foundation for Polish Science financed by the European Union under the European Regional Development Fund (POIR.04.04.00-00-3ED8/17). The authors thank Dr Hao Wu for the help with UPS measurements. This work was supported by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) - project number 424708673 and by the KAUST Office of Sponsored Research (OSR). Open Access funding provided by the Max Planck Society. S. Wang thanks the China Scholarship Council (CSC, 201906890035) for financial support. M. Mandal acknowledges postdoctoral support from the Alexander von Humboldt Foundation. T. Marszalek acknowledges the Foundation for Polish Science financed by the European Union under the European Regional Development Fund (POIR.04.04.00-00-3ED8/17). The authors thank Dr Hao Wu for the help with UPS measurements. This work was supported by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – project number 424708673 and by the KAUST Office of Sponsored Research (OSR). Open Access funding provided by the Max Planck Society.
Funders | Funder number |
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OSR | |
Alexander von Humboldt-Stiftung | |
European Commission | |
Deutsche Forschungsgemeinschaft | 424708673 |
Deutsche Forschungsgemeinschaft | |
King Abdullah University of Science and Technology | |
Max-Planck-Gesellschaft | |
China Scholarship Council | 201906890035 |
China Scholarship Council | |
European Regional Development Fund | POIR.04.04.00-00-3ED8/17 |
European Regional Development Fund |