Highly selective dermination of macromolecular chlorolignosulfonic acids in river and drinking water using Curie-point pyrolysis-gas chromatography-tandem mass spectroscopy.

A.-J. Bulterman; W.M.G.M. Loon; R.T. Ghijsen; U.A.T. Brinkman

doi:10.1021/es9607401

Highly selective dermination of macromolecular chlorolignosulfonic acids in river and drinking water using Curie-point pyrolysis-gas chromatography-tandem mass spectroscopy.

A.-J. Bulterman, W.M.G.M. Loon, R.T. Ghijsen, U.A.T. Brinkman

BioAnalytical Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

A highly selective pyrolysis-gas chromatography-tandem mass spectrometry (Py-GC-MS-MS) procedure for the quantitative determination of high molecular weight (MW > 1000) chlorolignosulfonic acids in river and drinking water is presented. The use of MS-MS considerably enhanced the selectivity toward 2- methoxy-5-chlorophenol (5-chloroguaiacol; a highly characteristic pyrolysis product of chlorolignosulfonic acids) as compared to SIM conditions. The dissociation of the parent ion at m/z 143 (C

Original language	English
Pages (from-to)	1946
Journal	Environmental Science and Technology
Volume	31
DOIs	https://doi.org/10.1021/es9607401
Publication status	Published - 1997

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title = "Highly selective dermination of macromolecular chlorolignosulfonic acids in river and drinking water using Curie-point pyrolysis-gas chromatography-tandem mass spectroscopy.",

abstract = "A highly selective pyrolysis-gas chromatography-tandem mass spectrometry (Py-GC-MS-MS) procedure for the quantitative determination of high molecular weight (MW > 1000) chlorolignosulfonic acids in river and drinking water is presented. The use of MS-MS considerably enhanced the selectivity toward 2- methoxy-5-chlorophenol (5-chloroguaiacol; a highly characteristic pyrolysis product of chlorolignosulfonic acids) as compared to SIM conditions. The dissociation of the parent ion at m/z 143 (C",

author = "A.-J. Bulterman and W.M.G.M. Loon and R.T. Ghijsen and U.A.T. Brinkman",

year = "1997",

doi = "10.1021/es9607401",

language = "English",

volume = "31",

pages = "1946",

journal = "Environmental Science and Technology",

issn = "0013-936X",

publisher = "American Chemical Society",

}

Highly selective dermination of macromolecular chlorolignosulfonic acids in river and drinking water using Curie-point pyrolysis-gas chromatography-tandem mass spectroscopy. / Bulterman, A.-J.; Loon, W.M.G.M.; Ghijsen, R.T. et al.

In: Environmental Science and Technology, Vol. 31, 1997, p. 1946.

Research output: Contribution to Journal › Article › Academic › peer-review

TY - JOUR

T1 - Highly selective dermination of macromolecular chlorolignosulfonic acids in river and drinking water using Curie-point pyrolysis-gas chromatography-tandem mass spectroscopy.

AU - Bulterman, A.-J.

AU - Loon, W.M.G.M.

AU - Ghijsen, R.T.

AU - Brinkman, U.A.T.

PY - 1997

Y1 - 1997

N2 - A highly selective pyrolysis-gas chromatography-tandem mass spectrometry (Py-GC-MS-MS) procedure for the quantitative determination of high molecular weight (MW > 1000) chlorolignosulfonic acids in river and drinking water is presented. The use of MS-MS considerably enhanced the selectivity toward 2- methoxy-5-chlorophenol (5-chloroguaiacol; a highly characteristic pyrolysis product of chlorolignosulfonic acids) as compared to SIM conditions. The dissociation of the parent ion at m/z 143 (C

AB - A highly selective pyrolysis-gas chromatography-tandem mass spectrometry (Py-GC-MS-MS) procedure for the quantitative determination of high molecular weight (MW > 1000) chlorolignosulfonic acids in river and drinking water is presented. The use of MS-MS considerably enhanced the selectivity toward 2- methoxy-5-chlorophenol (5-chloroguaiacol; a highly characteristic pyrolysis product of chlorolignosulfonic acids) as compared to SIM conditions. The dissociation of the parent ion at m/z 143 (C

U2 - 10.1021/es9607401

DO - 10.1021/es9607401

M3 - Article

SN - 0013-936X

VL - 31

SP - 1946

JO - Environmental Science and Technology

JF - Environmental Science and Technology

ER -

Highly selective dermination of macromolecular chlorolignosulfonic acids in river and drinking water using Curie-point pyrolysis-gas chromatography-tandem mass spectroscopy.

Abstract

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