Hypervalent carbon atom: "freezing" the S(N)2 transition state

S.C. Pierrefixe; S.J. van Stralen; J.N. van Stralen; C. Fonseca Guerra; F.M. Bickelhaupt

doi:10.1002/anie.200902125

Hypervalent carbon atom: "freezing" the S(N)2 transition state

S.C. Pierrefixe, S.J. van Stralen, J.N. van Stralen, C. Fonseca Guerra, F.M. Bickelhaupt

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN

Original language	English
Pages (from-to)	6469-71
Journal	Angewandte Chemie International Edition in English
Volume	48
Issue number	35
DOIs	https://doi.org/10.1002/anie.200902125
Publication status	Published - 2009

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10.1002/anie.200902125

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title = "Hypervalent carbon atom: {"}freezing{"} the S(N)2 transition state",

abstract = "High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN",

author = "S.C. Pierrefixe and {van Stralen}, S.J. and {van Stralen}, J.N. and {Fonseca Guerra}, C. and F.M. Bickelhaupt",

year = "2009",

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AU - Pierrefixe, S.C.

AU - van Stralen, S.J.

AU - van Stralen, J.N.

AU - Fonseca Guerra, C.

AU - Bickelhaupt, F.M.

PY - 2009

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N2 - High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN

AB - High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN

U2 - 10.1002/anie.200902125

DO - 10.1002/anie.200902125

M3 - Article

SN - 0570-0833

VL - 48

SP - 6469

EP - 6471

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 35

ER -

Hypervalent carbon atom: "freezing" the S(N)2 transition state

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