Hypervalent carbon atom: "freezing" the S(N)2 transition state

S.C. Pierrefixe; S.J. van Stralen; J.N. van Stralen; C. Fonseca Guerra; F.M. Bickelhaupt

doi:10.1002/anie.200902125

Hypervalent carbon atom: "freezing" the S(N)2 transition state

S.C. Pierrefixe
, S.J. van Stralen
, J.N. van Stralen
, C. Fonseca Guerra
, F.M. Bickelhaupt

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN

Original language	English
Pages (from-to)	6469-71
Journal	Angewandte Chemie International Edition in English
Volume	48
Issue number	35
DOIs	https://doi.org/10.1002/anie.200902125
Publication status	Published - 2009

Access to Document

10.1002/anie.200902125

Persistent URL (handle)

Persistent link

Cite this

@article{712599791f654c55af4eab66873a9fca,

title = "Hypervalent carbon atom: {"}freezing{"} the S(N)2 transition state",

abstract = "High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN",

author = "S.C. Pierrefixe and \{van Stralen\}, S.J. and \{van Stralen\}, J.N. and \{Fonseca Guerra\}, C. and F.M. Bickelhaupt",

year = "2009",

doi = "10.1002/anie.200902125",

language = "English",

volume = "48",

pages = "6469--71",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

number = "35",

}

TY - JOUR

T1 - Hypervalent carbon atom: "freezing" the S(N)2 transition state

AU - Pierrefixe, S.C.

AU - van Stralen, S.J.

AU - van Stralen, J.N.

AU - Fonseca Guerra, C.

AU - Bickelhaupt, F.M.

PY - 2009

Y1 - 2009

N2 - High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN

AB - High Five! Under certain circumstances a carbon atom can become hypervalent (see structure) and bind five substituents in the trigonal-bipyramidal structure, which is normally the labile SN

U2 - 10.1002/anie.200902125

DO - 10.1002/anie.200902125

M3 - Article

SN - 0570-0833

VL - 48

SP - 6469

EP - 6471

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 35

ER -

Hypervalent carbon atom: "freezing" the S(N)2 transition state

Abstract

Access to Document

Persistent URL (handle)

Fingerprint

Cite this