Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

G. Bucher; M.L.G. Borst; A.W. Ehlers; K. Lammertsma; S. Ceola; M. Huber; D. Grote; W. Sander

doi:10.1002/anie.200462862

Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

G. Bucher, M.L.G. Borst, A.W. Ehlers, K. Lammertsma, S. Ceola, M. Huber, D. Grote, W. Sander

Organic Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

(Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	3289-3293
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	44
Issue number	21
Early online date	17 May 2005
DOIs	https://doi.org/10.1002/anie.200462862
Publication status	Published - 20 May 2005

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title = "Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene",

abstract = "(Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. {\textcopyright} 2005 Wiley-VCH Verlag GmbH & Co. KGaA.",

author = "G. Bucher and M.L.G. Borst and A.W. Ehlers and K. Lammertsma and S. Ceola and M. Huber and D. Grote and W. Sander",

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AU - Bucher, G.

AU - Borst, M.L.G.

AU - Ehlers, A.W.

AU - Lammertsma, K.

AU - Ceola, S.

AU - Huber, M.

AU - Grote, D.

AU - Sander, W.

PY - 2005/5/20

Y1 - 2005/5/20

N2 - (Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - (Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

U2 - 10.1002/anie.200462862

DO - 10.1002/anie.200462862

M3 - Article

SN - 0570-0833

VL - 44

SP - 3289

EP - 3293

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 21

ER -

Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

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