Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

G. Bucher, M.L.G. Borst, A.W. Ehlers, K. Lammertsma, S. Ceola, M. Huber, D. Grote, W. Sander

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

(Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
Original languageEnglish
Pages (from-to)3289-3293
Number of pages4
JournalAngewandte Chemie International Edition in English
Volume44
Issue number21
Early online date17 May 2005
DOIs
Publication statusPublished - 20 May 2005

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