Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

G. Bucher; M.L.G. Borst; A.W. Ehlers; K. Lammertsma; S. Ceola; M. Huber; D. Grote; W. Sander

doi:10.1002/anie.200462862

Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

G. Bucher
, M.L.G. Borst
, A.W. Ehlers
, K. Lammertsma
, S. Ceola
, M. Huber
, D. Grote
, W. Sander

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

(Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	3289-3293
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	44
Issue number	21
Early online date	17 May 2005
DOIs	https://doi.org/10.1002/anie.200462862
Publication status	Published - 20 May 2005

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 6 Clean Water and Sanitation

Access to Document

10.1002/anie.200462862

Persistent URL (handle)

Persistent link

Cite this

@article{70a97a06edc74df59fe0bf6bf4611052,

title = "Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene",

abstract = "(Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. {\textcopyright} 2005 Wiley-VCH Verlag GmbH \& Co. KGaA.",

author = "G. Bucher and M.L.G. Borst and A.W. Ehlers and K. Lammertsma and S. Ceola and M. Huber and D. Grote and W. Sander",

year = "2005",

month = may,

day = "20",

doi = "10.1002/anie.200462862",

language = "English",

volume = "44",

pages = "3289--3293",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

number = "21",

}

TY - JOUR

T1 - Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

AU - Bucher, G.

AU - Borst, M.L.G.

AU - Ehlers, A.W.

AU - Lammertsma, K.

AU - Ceola, S.

AU - Huber, M.

AU - Grote, D.

AU - Sander, W.

PY - 2005/5/20

Y1 - 2005/5/20

N2 - (Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - (Chemical Equation Presented) Monitoring the cleavage of phosphiranes 1 and 2 by using a variety of low-temperature and time-resolved spectroscopic techniques has shown that triplet mesitylphosphinidene (3) is the principal product of this photolytic reaction (see scheme). Results obtained by using laser flash photolysis show that 3 is readily quenched by reactive π systems. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

U2 - 10.1002/anie.200462862

DO - 10.1002/anie.200462862

M3 - Article

SN - 0570-0833

VL - 44

SP - 3289

EP - 3293

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 21

ER -

Infrared, UV/Vis, and W-band EPR spectroscopic characterization and photochemistry of triplet mesitylphosphinidene

Abstract

UN SDGs

Access to Document

Persistent URL (handle)

Fingerprint

Cite this