Isomer-specific detection of azaarenes in environmental samples by Shpol'skii luminescence spectroscopy.

I.S. Kozin; O.F.A. Larsen; P. de Voogt; C. Gooijer; N.H. Velthorst

doi:10.1016/S0003-2670(97)00446-7

Isomer-specific detection of azaarenes in environmental samples by Shpol'skii luminescence spectroscopy.

I.S. Kozin, O.F.A. Larsen, P. de Voogt, C. Gooijer, N.H. Velthorst

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

An isomer-specific detection method based on Shpol'skii spectroscopy, a cryogenic high-resolution luminescence technique, has been developed to enable determination of nitrogen-containing in-ring substituted polycyclic aromatic compounds in environmental samples. Using conventional lamp excitation in combination with fluorescence and phosphorescence emission, a number of individual benzo- and dibenzacridines as well as 1-azapyrene have been unambiguously identified and quantitatively determined in river and lake sediment samples collected from selected sites in The Netherlands. The limits of detection observed for the examined aza-PACs are in the 10-100 picogram range.

Original language	English
Pages (from-to)	181
Journal	Analytica Chimica Acta
Volume	354
DOIs	https://doi.org/10.1016/S0003-2670(97)00446-7
Publication status	Published - 1997

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10.1016/S0003-2670(97)00446-7

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title = "Isomer-specific detection of azaarenes in environmental samples by Shpol'skii luminescence spectroscopy.",

abstract = "An isomer-specific detection method based on Shpol'skii spectroscopy, a cryogenic high-resolution luminescence technique, has been developed to enable determination of nitrogen-containing in-ring substituted polycyclic aromatic compounds in environmental samples. Using conventional lamp excitation in combination with fluorescence and phosphorescence emission, a number of individual benzo- and dibenzacridines as well as 1-azapyrene have been unambiguously identified and quantitatively determined in river and lake sediment samples collected from selected sites in The Netherlands. The limits of detection observed for the examined aza-PACs are in the 10-100 picogram range.",

author = "I.S. Kozin and O.F.A. Larsen and {de Voogt}, P. and C. Gooijer and N.H. Velthorst",

year = "1997",

doi = "10.1016/S0003-2670(97)00446-7",

language = "English",

volume = "354",

pages = "181",

journal = "Analytica Chimica Acta",

issn = "0003-2670",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Isomer-specific detection of azaarenes in environmental samples by Shpol'skii luminescence spectroscopy.

AU - Kozin, I.S.

AU - Larsen, O.F.A.

AU - de Voogt, P.

AU - Gooijer, C.

AU - Velthorst, N.H.

PY - 1997

Y1 - 1997

N2 - An isomer-specific detection method based on Shpol'skii spectroscopy, a cryogenic high-resolution luminescence technique, has been developed to enable determination of nitrogen-containing in-ring substituted polycyclic aromatic compounds in environmental samples. Using conventional lamp excitation in combination with fluorescence and phosphorescence emission, a number of individual benzo- and dibenzacridines as well as 1-azapyrene have been unambiguously identified and quantitatively determined in river and lake sediment samples collected from selected sites in The Netherlands. The limits of detection observed for the examined aza-PACs are in the 10-100 picogram range.

AB - An isomer-specific detection method based on Shpol'skii spectroscopy, a cryogenic high-resolution luminescence technique, has been developed to enable determination of nitrogen-containing in-ring substituted polycyclic aromatic compounds in environmental samples. Using conventional lamp excitation in combination with fluorescence and phosphorescence emission, a number of individual benzo- and dibenzacridines as well as 1-azapyrene have been unambiguously identified and quantitatively determined in river and lake sediment samples collected from selected sites in The Netherlands. The limits of detection observed for the examined aza-PACs are in the 10-100 picogram range.

U2 - 10.1016/S0003-2670(97)00446-7

DO - 10.1016/S0003-2670(97)00446-7

M3 - Article

SN - 0003-2670

VL - 354

SP - 181

JO - Analytica Chimica Acta

JF - Analytica Chimica Acta

ER -

Isomer-specific detection of azaarenes in environmental samples by Shpol'skii luminescence spectroscopy.

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