TY - JOUR
T1 - Isomer-specific detection of PAHs and PAH metabolites in environmental matrices by Shpol'skii luminescence spectroscopy.
AU - Kozin, I.
AU - Gooijer, C.
AU - Velthorst, N.H.
AU - Hellou, J.
AU - Zitko, V.
N1 - 1447
PY - 1996
Y1 - 1996
N2 - Shpol'skii Spectroscopy, a high-resolution low temperature molecular luminescence technique, was applied to the analysis of various complex environmental matrices to obtain isomer specific information on a wide range of polycyclic aromatic hydrocarbons (PAHs) and their derivatives. Using conventional lamp excitation and fluorescence and phosphorescence detection, parent priority PAHs, six-membered ring compounds (e, g. potent carcinogens, dibenzopyrenes), and methyl-substituted PAHs were determined in crude and purified lubricating oil sample, extracts of sediment, and muscle from finfish. In addition, detection of major PAH metabolites (hydroxy-substituted PAHs) in gall bladder of fish is demonstrated by applying conventional lamp and Laser Excited Shpol'skii Spectroscopy (LESS).
AB - Shpol'skii Spectroscopy, a high-resolution low temperature molecular luminescence technique, was applied to the analysis of various complex environmental matrices to obtain isomer specific information on a wide range of polycyclic aromatic hydrocarbons (PAHs) and their derivatives. Using conventional lamp excitation and fluorescence and phosphorescence detection, parent priority PAHs, six-membered ring compounds (e, g. potent carcinogens, dibenzopyrenes), and methyl-substituted PAHs were determined in crude and purified lubricating oil sample, extracts of sediment, and muscle from finfish. In addition, detection of major PAH metabolites (hydroxy-substituted PAHs) in gall bladder of fish is demonstrated by applying conventional lamp and Laser Excited Shpol'skii Spectroscopy (LESS).
U2 - 10.1016/0045-6535(96)00282-2
DO - 10.1016/0045-6535(96)00282-2
M3 - Article
SN - 0045-6535
VL - 33
SP - 1435
EP - 1447
JO - Chemosphere
JF - Chemosphere
IS - 8
ER -
