Isomerization of 2-phospha-4-silabicyclo[1.10]butane

J.C. Slootweg; A.W. Ehlers; K. Lammertsma

doi:10.1080/10426500490427187

Isomerization of 2-phospha-4-silabicyclo[1.10]butane

J.C. Slootweg, A.W. Ehlers, K. Lammertsma

Organic Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

In analogy with the valence isomerism of the hydrocarbons bicyclobutane, 1,3-butadiene and cyclobutene, the rearrangements for 2-phospha-4-sila- bicyclo[1.1.0]butane were studied at the B3LYP/6-311+G** level of theory. The monocyclic 1,2-dihydro-1,2-phosphasilete is shown to be the thermodynamically preferred product, in contrast to the isomerism of the hydrocarbons that favors the 1,3-butadiene structure.

Original language	English
Pages (from-to)	803-807
Number of pages	4
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	179
DOIs	https://doi.org/10.1080/10426500490427187
Publication status	Published - 2004

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title = "Isomerization of 2-phospha-4-silabicyclo[1.10]butane",

abstract = "In analogy with the valence isomerism of the hydrocarbons bicyclobutane, 1,3-butadiene and cyclobutene, the rearrangements for 2-phospha-4-sila- bicyclo[1.1.0]butane were studied at the B3LYP/6-311+G** level of theory. The monocyclic 1,2-dihydro-1,2-phosphasilete is shown to be the thermodynamically preferred product, in contrast to the isomerism of the hydrocarbons that favors the 1,3-butadiene structure.",

author = "J.C. Slootweg and A.W. Ehlers and K. Lammertsma",

year = "2004",

doi = "10.1080/10426500490427187",

language = "English",

volume = "179",

pages = "803--807",

journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

issn = "1042-6507",

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T1 - Isomerization of 2-phospha-4-silabicyclo[1.10]butane

AU - Slootweg, J.C.

AU - Ehlers, A.W.

AU - Lammertsma, K.

PY - 2004

Y1 - 2004

N2 - In analogy with the valence isomerism of the hydrocarbons bicyclobutane, 1,3-butadiene and cyclobutene, the rearrangements for 2-phospha-4-sila- bicyclo[1.1.0]butane were studied at the B3LYP/6-311+G** level of theory. The monocyclic 1,2-dihydro-1,2-phosphasilete is shown to be the thermodynamically preferred product, in contrast to the isomerism of the hydrocarbons that favors the 1,3-butadiene structure.

AB - In analogy with the valence isomerism of the hydrocarbons bicyclobutane, 1,3-butadiene and cyclobutene, the rearrangements for 2-phospha-4-sila- bicyclo[1.1.0]butane were studied at the B3LYP/6-311+G** level of theory. The monocyclic 1,2-dihydro-1,2-phosphasilete is shown to be the thermodynamically preferred product, in contrast to the isomerism of the hydrocarbons that favors the 1,3-butadiene structure.

U2 - 10.1080/10426500490427187

DO - 10.1080/10426500490427187

M3 - Article

VL - 179

SP - 803

EP - 807

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

SN - 1042-6507

ER -

Isomerization of 2-phospha-4-silabicyclo[1.10]butane

Abstract

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