Linkage isomerism of nitriles in rhodium half-sandwich metallacycles

L. Orian; W.J. van Zeist; F.M. Bickelhaupt

doi:10.1021/om8004614

Linkage isomerism of nitriles in rhodium half-sandwich metallacycles

L. Orian
, W.J. van Zeist
, F.M. Bickelhaupt

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

A systematic analysis of the linkage isomerism of nitriles in half-sandwich five-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods. © 2008 American Chemical Society.

Original language	English
Pages (from-to)	4028-4030
Journal	Organometallics
Volume	27
Issue number	16
DOIs	https://doi.org/10.1021/om8004614
Publication status	Published - 2008

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10.1021/om8004614

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title = "Linkage isomerism of nitriles in rhodium half-sandwich metallacycles",

abstract = "A systematic analysis of the linkage isomerism of nitriles in half-sandwich five-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods. {\textcopyright} 2008 American Chemical Society.",

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AU - Bickelhaupt, F.M.

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Y1 - 2008

N2 - A systematic analysis of the linkage isomerism of nitriles in half-sandwich five-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods. © 2008 American Chemical Society.

AB - A systematic analysis of the linkage isomerism of nitriles in half-sandwich five-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods. © 2008 American Chemical Society.

U2 - 10.1021/om8004614

DO - 10.1021/om8004614

M3 - Article

SN - 1520-6041

VL - 27

SP - 4028

EP - 4030

JO - Organometallics

JF - Organometallics

IS - 16

ER -

Linkage isomerism of nitriles in rhodium half-sandwich metallacycles

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