Magnetic balance and explicit diamagnetic expressions for nuclear magnetic resonance shielding tensors

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    Abstract

    Two recently proposed formally exact theories for the relativistic calculation of nuclear shielding tensors are numerically evaluated for the xenon atom and the hydrogen fluoride and hydrogen iodide molecules. Both theories are shown to yield significantly different shieldings and partitionings into diamagnetic and paramagnetic contributions. A short analysis is given and directions for further research are indicated. © 2005 Elsevier Inc. All rights reserved.
    Original languageEnglish
    Pages (from-to)369-381
    JournalAdvances in Quantum Chemistry
    Volume48
    DOIs
    Publication statusPublished - 2005

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