Measuring Ultrafast Spectral Diffusion and Correlation Dynamics by Two-Dimensional Electronic Spectroscopy

T.N. Do; M.F. Khyasudeen; P.J. Nowakowski; Z. Zhang; H.-S. Tan

doi:10.1002/asia.201900994

Measuring Ultrafast Spectral Diffusion and Correlation Dynamics by Two-Dimensional Electronic Spectroscopy

T.N. Do, M.F. Khyasudeen, P.J. Nowakowski, Z. Zhang, H.-S. Tan

Research output: Contribution to Journal › Review article › Academic › peer-review

Abstract

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimThe frequency fluctuation correlation function (FFCF) measures the spectral diffusion of a state's transition while the frequency fluctuation cross-correlation function (FXCF) measures the correlation dynamics between the transitions of two separate states. These quantities contain a wealth of information on how the chromophores or excitonic states interact and couple with its environment and with each other. We summarize the experimental implementations and theoretical considerations of using two-dimensional electronic spectroscopy to characterize FFCFs and FXCFs. Applications can be found in systems such as the chlorophyll pigment molecules in light-harvesting complexes and CdSe nanomaterials.

Original language	English
Pages (from-to)	3992-4000
Journal	Chemistry - An Asian Journal
Volume	14
Issue number	22
DOIs	https://doi.org/10.1002/asia.201900994
Publication status	Published - 18 Nov 2019
Externally published	Yes

Funding

This work is supported by grants from the Singapore Ministry of Education Academic Research Fund (Tier 2 MOE2015-T2-1–039 and Tier 1 RG16/15).

Funders	Funder number
Singapore Ministry of Education Academic Research Fund	1 RG16/15, MOE2015-T2-1–039

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title = "Measuring Ultrafast Spectral Diffusion and Correlation Dynamics by Two-Dimensional Electronic Spectroscopy",

abstract = "{\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, WeinheimThe frequency fluctuation correlation function (FFCF) measures the spectral diffusion of a state's transition while the frequency fluctuation cross-correlation function (FXCF) measures the correlation dynamics between the transitions of two separate states. These quantities contain a wealth of information on how the chromophores or excitonic states interact and couple with its environment and with each other. We summarize the experimental implementations and theoretical considerations of using two-dimensional electronic spectroscopy to characterize FFCFs and FXCFs. Applications can be found in systems such as the chlorophyll pigment molecules in light-harvesting complexes and CdSe nanomaterials.",

author = "T.N. Do and M.F. Khyasudeen and P.J. Nowakowski and Z. Zhang and H.-S. Tan",

year = "2019",

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doi = "10.1002/asia.201900994",

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T1 - Measuring Ultrafast Spectral Diffusion and Correlation Dynamics by Two-Dimensional Electronic Spectroscopy

AU - Do, T.N.

AU - Khyasudeen, M.F.

AU - Nowakowski, P.J.

AU - Zhang, Z.

AU - Tan, H.-S.

PY - 2019/11/18

Y1 - 2019/11/18

N2 - © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimThe frequency fluctuation correlation function (FFCF) measures the spectral diffusion of a state's transition while the frequency fluctuation cross-correlation function (FXCF) measures the correlation dynamics between the transitions of two separate states. These quantities contain a wealth of information on how the chromophores or excitonic states interact and couple with its environment and with each other. We summarize the experimental implementations and theoretical considerations of using two-dimensional electronic spectroscopy to characterize FFCFs and FXCFs. Applications can be found in systems such as the chlorophyll pigment molecules in light-harvesting complexes and CdSe nanomaterials.

AB - © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimThe frequency fluctuation correlation function (FFCF) measures the spectral diffusion of a state's transition while the frequency fluctuation cross-correlation function (FXCF) measures the correlation dynamics between the transitions of two separate states. These quantities contain a wealth of information on how the chromophores or excitonic states interact and couple with its environment and with each other. We summarize the experimental implementations and theoretical considerations of using two-dimensional electronic spectroscopy to characterize FFCFs and FXCFs. Applications can be found in systems such as the chlorophyll pigment molecules in light-harvesting complexes and CdSe nanomaterials.

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U2 - 10.1002/asia.201900994

DO - 10.1002/asia.201900994

M3 - Review article

SN - 1861-4728

VL - 14

SP - 3992

EP - 4000

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 22

ER -

Measuring Ultrafast Spectral Diffusion and Correlation Dynamics by Two-Dimensional Electronic Spectroscopy

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