TY - JOUR
T1 - Monofluorinated polycyclic aromatic hydrocarbons as internal standards in Shpol'skii spectroscopy: 1-fluoropyrene as an example
AU - luthe, G.
AU - Es-Sbai, H.
AU - Gooijer, C.
AU - Brinkman, U.A.T.
AU - Ariese, F.
PY - 2002
Y1 - 2002
N2 - As a sequel to an earlier paper, we have studied the behaviour of 1-fluoropyrene and pyrene in lamp-excited Shpol'skii spectrofluorimetry at 11K in two different matrices, n-octane and n-hexane, using two different solidification processes. Particular attention is paid to the suitability of 1-fluoropyrene as an internal standard (IS) to correct for different sources of variability. As a demonstration of the applicability of this approach, four polycyclic aromatic hydrocarbons (PAHs; pyrene, chrysene, benzo[a]pyrene and benzo[k]fluoranthene) were determined in a river sediment extract. The results agreed well with those obtained by HPLC with fluorescence detection. © 2002 Elsevier Science B.V. All rights reserved.
AB - As a sequel to an earlier paper, we have studied the behaviour of 1-fluoropyrene and pyrene in lamp-excited Shpol'skii spectrofluorimetry at 11K in two different matrices, n-octane and n-hexane, using two different solidification processes. Particular attention is paid to the suitability of 1-fluoropyrene as an internal standard (IS) to correct for different sources of variability. As a demonstration of the applicability of this approach, four polycyclic aromatic hydrocarbons (PAHs; pyrene, chrysene, benzo[a]pyrene and benzo[k]fluoranthene) were determined in a river sediment extract. The results agreed well with those obtained by HPLC with fluorescence detection. © 2002 Elsevier Science B.V. All rights reserved.
U2 - 10.1016/S0003-2670(02)00109-5
DO - 10.1016/S0003-2670(02)00109-5
M3 - Article
SN - 0003-2670
VL - 459
SP - 53
EP - 59
JO - Analytica Chimica Acta
JF - Analytica Chimica Acta
IS - 1
ER -
