N-heterocyclic carbene-functionalized ruthenium phosphinidenes: what a difference a twist makes

H. Aktas; J.C. Slootweg; M. Schakel; A.W. Ehlers; M. Lutz; A.L Spek; K. Lammertsma

doi:10.1021/ja901540h

N-heterocyclic carbene-functionalized ruthenium phosphinidenes: what a difference a twist makes

H. Aktas, J.C. Slootweg, M. Schakel, A.W. Ehlers, M. Lutz, A.L Spek, K. Lammertsma

Organic Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

(Figure Presented) Catalyst tuning by changing ligands is a well-established protocol in transition-metal chemistry. N-Heterocyclic carbenes (NHCs) and tertiary phosphines (R<inf>3</inf>P) are the ubiquitous ligand actors. Here we demonstrate that the relative σ-donor/π-acceptor ability of the NHC ligand itself can be influenced by a simple substituent-controlled conformational change, thereby directly impacting the reactivity of the transition-metal complex. Copyright © 2009 American Chemical Society.

Original language	English
Pages (from-to)	6666-7
Journal	Journal of the American Chemical Society
Volume	131
Issue number	19
DOIs	https://doi.org/10.1021/ja901540h
Publication status	Published - 2009

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CCDC 736911: Experimental Crystal Structure Determination
Aktas, H. (Contributor), Slootweg, J. C. (Contributor), Schakel, M. (Contributor), Ehlers, A. W. (Contributor), Lutz, M. (Contributor), Spek, A. L. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Jan 2010
DOI: 10.5517/ccsqtbm, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsqtbm&sid=DataCite
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title = "N-heterocyclic carbene-functionalized ruthenium phosphinidenes: what a difference a twist makes",

abstract = "(Figure Presented) Catalyst tuning by changing ligands is a well-established protocol in transition-metal chemistry. N-Heterocyclic carbenes (NHCs) and tertiary phosphines (R3P) are the ubiquitous ligand actors. Here we demonstrate that the relative σ-donor/π-acceptor ability of the NHC ligand itself can be influenced by a simple substituent-controlled conformational change, thereby directly impacting the reactivity of the transition-metal complex. Copyright {\textcopyright} 2009 American Chemical Society.",

author = "H. Aktas and J.C. Slootweg and M. Schakel and A.W. Ehlers and M. Lutz and A.L Spek and K. Lammertsma",

year = "2009",

doi = "10.1021/ja901540h",

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journal = "Journal of the American Chemical Society",

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T1 - N-heterocyclic carbene-functionalized ruthenium phosphinidenes: what a difference a twist makes

AU - Aktas, H.

AU - Slootweg, J.C.

AU - Schakel, M.

AU - Ehlers, A.W.

AU - Lutz, M.

AU - Spek, A.L

AU - Lammertsma, K.

PY - 2009

Y1 - 2009

N2 - (Figure Presented) Catalyst tuning by changing ligands is a well-established protocol in transition-metal chemistry. N-Heterocyclic carbenes (NHCs) and tertiary phosphines (R3P) are the ubiquitous ligand actors. Here we demonstrate that the relative σ-donor/π-acceptor ability of the NHC ligand itself can be influenced by a simple substituent-controlled conformational change, thereby directly impacting the reactivity of the transition-metal complex. Copyright © 2009 American Chemical Society.

AB - (Figure Presented) Catalyst tuning by changing ligands is a well-established protocol in transition-metal chemistry. N-Heterocyclic carbenes (NHCs) and tertiary phosphines (R3P) are the ubiquitous ligand actors. Here we demonstrate that the relative σ-donor/π-acceptor ability of the NHC ligand itself can be influenced by a simple substituent-controlled conformational change, thereby directly impacting the reactivity of the transition-metal complex. Copyright © 2009 American Chemical Society.

U2 - 10.1021/ja901540h

DO - 10.1021/ja901540h

M3 - Article

SN - 0002-7863

VL - 131

SP - 6666

EP - 6667

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 19

ER -

N-heterocyclic carbene-functionalized ruthenium phosphinidenes: what a difference a twist makes

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CCDC 736911: Experimental Crystal Structure Determination

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