Abstract
We demonstrate that with a thin film based fiber optic sensor it is possible to quantitatively determine the hydrogen concentration over a wide pressure range using a Pd-Au alloy as H2 sensitive layer. The optical properties of the Pd-Au sensing layer change in an almost one-to-one relation with the hydrogen pressure when the Au concentration is varied between 18 at.% and 36 at.%. Thus we measure the hydrogen pressure continuously and quantitatively up to ~250 mbar in reflection mode at room temperature. The response time during absorption and desorption is typically less than 15 s, which is fast enough for
sensing applications. The addition of O2 (up to 2%) and CH4 (up to 5%) to the feed flow has little or no influence on the measured hydrogen pressure. In contrast, CO affects the sensor’s response even at concentrations as low as 19 ppm. The Pd-Au fiber optic sensor shows a high reproducibility and remains optically and mechanically stable up to at least ~250 hydrogenation cycles without any indication of degradation.
sensing applications. The addition of O2 (up to 2%) and CH4 (up to 5%) to the feed flow has little or no influence on the measured hydrogen pressure. In contrast, CO affects the sensor’s response even at concentrations as low as 19 ppm. The Pd-Au fiber optic sensor shows a high reproducibility and remains optically and mechanically stable up to at least ~250 hydrogenation cycles without any indication of degradation.
Original language | English |
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Pages (from-to) | 4201-4212 |
Number of pages | 12 |
Journal | International Journal of Hydrogen Energy |
Volume | 38 |
DOIs | |
Publication status | Published - 13 Feb 2013 |