Nanostructured Pd-Au based fiber optic sensors for probing hydrogen concentrations in gas mixtures

R.J. Westerwaal, J.S.A. Rooijmans, L. Leclercq, D. Gheorghe, T. Radeva, L. Mooij, T. Mak, Leo Polak, Martin Slaman, B. Dam, Th Rasing

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

We demonstrate that with a thin film based fiber optic sensor it is possible to quantitatively determine the hydrogen concentration over a wide pressure range using a Pd-Au alloy as H2 sensitive layer. The optical properties of the Pd-Au sensing layer change in an almost one-to-one relation with the hydrogen pressure when the Au concentration is varied between 18 at.% and 36 at.%. Thus we measure the hydrogen pressure continuously and quantitatively up to ~250 mbar in reflection mode at room temperature. The response time during absorption and desorption is typically less than 15 s, which is fast enough for
sensing applications. The addition of O2 (up to 2%) and CH4 (up to 5%) to the feed flow has little or no influence on the measured hydrogen pressure. In contrast, CO affects the sensor’s response even at concentrations as low as 19 ppm. The Pd-Au fiber optic sensor shows a high reproducibility and remains optically and mechanically stable up to at least ~250 hydrogenation cycles without any indication of degradation.
Original languageEnglish
Pages (from-to)4201-4212
Number of pages12
JournalInternational Journal of Hydrogen Energy
Volume38
DOIs
Publication statusPublished - 13 Feb 2013

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