Novel Bis(azido)phosphole building block for extended π-conjugated systems

W. Weymiens; F. Hartl; M. Lutz; J.C. Slootweg; A.W. Ehlers; K. Lammertsma

doi:10.1002/ejoc.201201148

Novel Bis(azido)phosphole building block for extended π-conjugated systems

W. Weymiens, F. Hartl, M. Lutz, J.C. Slootweg, A.W. Ehlers, K. Lammertsma

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Abstract

Novel bis(azidophenyl)phosphole sulfide building block 8 has been developed to give access to a plethora of phosphole-containing π-conjugated systems in a simple synthetic step. This was explored for the reaction of the two azido moieties with phenyl-, pyridyl- and thienylacetylenes, to give bis(aryltriazolyl)-extended π-systems, having either the phosphole sulfide (9) or the phosphole (10) group as central ring. These conjugated frameworks exhibit intriguing photophysical and electrochemical properties that vary with the nature of the aromatic end-group. The λ

Original language	English
Pages (from-to)	6711-6721
Journal	European Journal of Organic Chemistry
Volume	34
Early online date	25 Oct 2012
DOIs	https://doi.org/10.1002/ejoc.201201148
Publication status	Published - 2012

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CCDC 853315: Experimental Crystal Structure Determination
Weymiens, W. (Contributor), Hartl, F. (Contributor), Lutz, M. (Contributor), Slootweg, J. C. (Contributor), Ehlers, A. W. (Contributor), Mulder, J. R. (Contributor) & Lammertsma, K. (Contributor), Unknown Publisher, 1 Dec 2012
DOI: 10.5517/ccxmy9r, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxmy9r&sid=DataCite
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abstract = "Novel bis(azidophenyl)phosphole sulfide building block 8 has been developed to give access to a plethora of phosphole-containing π-conjugated systems in a simple synthetic step. This was explored for the reaction of the two azido moieties with phenyl-, pyridyl- and thienylacetylenes, to give bis(aryltriazolyl)-extended π-systems, having either the phosphole sulfide (9) or the phosphole (10) group as central ring. These conjugated frameworks exhibit intriguing photophysical and electrochemical properties that vary with the nature of the aromatic end-group. The λ",

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language = "English",

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T1 - Novel Bis(azido)phosphole building block for extended π-conjugated systems

AU - Weymiens, W.

AU - Hartl, F.

AU - Lutz, M.

AU - Slootweg, J.C.

AU - Ehlers, A.W.

AU - Lammertsma, K.

PY - 2012

Y1 - 2012

N2 - Novel bis(azidophenyl)phosphole sulfide building block 8 has been developed to give access to a plethora of phosphole-containing π-conjugated systems in a simple synthetic step. This was explored for the reaction of the two azido moieties with phenyl-, pyridyl- and thienylacetylenes, to give bis(aryltriazolyl)-extended π-systems, having either the phosphole sulfide (9) or the phosphole (10) group as central ring. These conjugated frameworks exhibit intriguing photophysical and electrochemical properties that vary with the nature of the aromatic end-group. The λ

AB - Novel bis(azidophenyl)phosphole sulfide building block 8 has been developed to give access to a plethora of phosphole-containing π-conjugated systems in a simple synthetic step. This was explored for the reaction of the two azido moieties with phenyl-, pyridyl- and thienylacetylenes, to give bis(aryltriazolyl)-extended π-systems, having either the phosphole sulfide (9) or the phosphole (10) group as central ring. These conjugated frameworks exhibit intriguing photophysical and electrochemical properties that vary with the nature of the aromatic end-group. The λ

U2 - 10.1002/ejoc.201201148

DO - 10.1002/ejoc.201201148

M3 - Article

SN - 1434-193X

VL - 34

SP - 6711

EP - 6721

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

ER -

Novel Bis(azido)phosphole building block for extended π-conjugated systems

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CCDC 853315: Experimental Crystal Structure Determination

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