Nucleophilic substitution at phosphorus (S(N)2@P): disappearance and reappearance of reaction barriers

M.A. van Bochove; M. Swart; F.M. Bickelhaupt

doi:10.1021/ja0606529

Nucleophilic substitution at phosphorus (S(N)2@P): disappearance and reappearance of reaction barriers

M.A. van Bochove, M. Swart, F.M. Bickelhaupt

Theoretical Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Pentacoordinate phosphorus species play a key role in organic and biological processes. Yet, their nature is still not fully understood, in particular, whether they are stable, intermediate transition complexes (TC) or labile transition states (TS). Through systematic, theoretical analyses of elementary S

Original language	English
Pages (from-to)	10738-44
Journal	Journal of the American Chemical Society
Volume	128
Issue number	33
DOIs	https://doi.org/10.1021/ja0606529
Publication status	Published - 2006

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10.1021/ja0606529

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title = "Nucleophilic substitution at phosphorus (S(N)2@P): disappearance and reappearance of reaction barriers",

abstract = "Pentacoordinate phosphorus species play a key role in organic and biological processes. Yet, their nature is still not fully understood, in particular, whether they are stable, intermediate transition complexes (TC) or labile transition states (TS). Through systematic, theoretical analyses of elementary S",

author = "{van Bochove}, M.A. and M. Swart and F.M. Bickelhaupt",

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AU - Swart, M.

AU - Bickelhaupt, F.M.

PY - 2006

Y1 - 2006

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AB - Pentacoordinate phosphorus species play a key role in organic and biological processes. Yet, their nature is still not fully understood, in particular, whether they are stable, intermediate transition complexes (TC) or labile transition states (TS). Through systematic, theoretical analyses of elementary S

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DO - 10.1021/ja0606529

M3 - Article

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EP - 10744

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 33

ER -

Nucleophilic substitution at phosphorus (S(N)2@P): disappearance and reappearance of reaction barriers

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