Nucleophilic substitution at phosphorus (S(N)2@P): disappearance and reappearance of reaction barriers

M.A. van Bochove, M. Swart, F.M. Bickelhaupt

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Pentacoordinate phosphorus species play a key role in organic and biological processes. Yet, their nature is still not fully understood, in particular, whether they are stable, intermediate transition complexes (TC) or labile transition states (TS). Through systematic, theoretical analyses of elementary S
Original languageEnglish
Pages (from-to)10738-44
JournalJournal of the American Chemical Society
Volume128
Issue number33
DOIs
Publication statusPublished - 2006

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