Optical observation of the 3s sigma F-g (3)Pi(u) Rydberg state of N-2

J.P. Sprengers; E.M. Reinhold; W.M.G. Ubachs; K.G.H. Baldwin; B.R. Lewis

Optical observation of the 3s sigma F-g (3)Pi(u) Rydberg state of N-2

J.P. Sprengers, E.M. Reinhold, W.M.G. Ubachs, K.G.H. Baldwin, B.R. Lewis

Quantum Metrology & Laser Applications

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Abstract

Using ultrahigh-resolution 1 XUV+1 UV two-photon ionization laser spectroscopy, the F (3)Pi(u)<- X (1)Sigma(g)(+)(0,0) transition of N-2 has been optically observed for the first time, and the 3s sigma(g)F (3)Pi(u)(upsilon=0) Rydberg level fully characterized with rotational resolution. The experimental spectroscopic parameters and predissociation level widths suggest strong interactions between the F state and the 3p pi(u)G (3)Pi(u) Rydberg and C-' (3)Pi(u) valence states, analogous to those well known in the case of the isoconfigurational (1)Pi(u) states. (c) 2005 American Institute of Physics.

Original language	English
Pages (from-to)	144315
Journal	Journal of Chemical Physics
Volume	123
Issue number	14
Publication status	Published - 2005

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title = "Optical observation of the 3s sigma F-g (3)Pi(u) Rydberg state of N-2",

abstract = "Using ultrahigh-resolution 1 XUV+1 UV two-photon ionization laser spectroscopy, the F (3)Pi(u)<- X (1)Sigma(g)(+)(0,0) transition of N-2 has been optically observed for the first time, and the 3s sigma(g)F (3)Pi(u)(upsilon=0) Rydberg level fully characterized with rotational resolution. The experimental spectroscopic parameters and predissociation level widths suggest strong interactions between the F state and the 3p pi(u)G (3)Pi(u) Rydberg and C-' (3)Pi(u) valence states, analogous to those well known in the case of the isoconfigurational (1)Pi(u) states. (c) 2005 American Institute of Physics.",

author = "J.P. Sprengers and E.M. Reinhold and W.M.G. Ubachs and K.G.H. Baldwin and B.R. Lewis",

year = "2005",

language = "English",

volume = "123",

pages = "144315",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "14",

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TY - JOUR

T1 - Optical observation of the 3s sigma F-g (3)Pi(u) Rydberg state of N-2

AU - Sprengers, J.P.

AU - Reinhold, E.M.

AU - Ubachs, W.M.G.

AU - Baldwin, K.G.H.

AU - Lewis, B.R.

PY - 2005

Y1 - 2005

N2 - Using ultrahigh-resolution 1 XUV+1 UV two-photon ionization laser spectroscopy, the F (3)Pi(u)<- X (1)Sigma(g)(+)(0,0) transition of N-2 has been optically observed for the first time, and the 3s sigma(g)F (3)Pi(u)(upsilon=0) Rydberg level fully characterized with rotational resolution. The experimental spectroscopic parameters and predissociation level widths suggest strong interactions between the F state and the 3p pi(u)G (3)Pi(u) Rydberg and C-' (3)Pi(u) valence states, analogous to those well known in the case of the isoconfigurational (1)Pi(u) states. (c) 2005 American Institute of Physics.

AB - Using ultrahigh-resolution 1 XUV+1 UV two-photon ionization laser spectroscopy, the F (3)Pi(u)<- X (1)Sigma(g)(+)(0,0) transition of N-2 has been optically observed for the first time, and the 3s sigma(g)F (3)Pi(u)(upsilon=0) Rydberg level fully characterized with rotational resolution. The experimental spectroscopic parameters and predissociation level widths suggest strong interactions between the F state and the 3p pi(u)G (3)Pi(u) Rydberg and C-' (3)Pi(u) valence states, analogous to those well known in the case of the isoconfigurational (1)Pi(u) states. (c) 2005 American Institute of Physics.

M3 - Article

SN - 0021-9606

VL - 123

SP - 144315

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 14

ER -

Optical observation of the 3s sigma F-g (3)Pi(u) Rydberg state of N-2

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