Parameter precision in global analysis of time resolved spectra.

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    Abstract

    By means of simulation parameter estimation in global analysis of time resolved spectra was studied. Kinetic, spectral as well as spectrotemporal models were used to describe a system consisting of an inherent mixture of components whose concentrations change with time. With a single component the parameter precision did not differ between the different model types. With two or more components the precision decreases with a kinetic or spectral model because of overlap between concentration profiles or spectra of the components. However, with a spectrotemporal model the decrease is much less, and equals zero with zero spectral overlap. © 1997 IEEE.
    Original languageEnglish
    Pages (from-to)764-768
    JournalIEEE Transactions on Instrumentation and Measurement
    Volume46
    DOIs
    Publication statusPublished - 1997

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