Paratethys pacing of the Messinian Salinity Crisis: Low salinity waters contributing to gypsum precipitation?

Arjen Grothe, Federico Andreetto, Gert Jan Reichart, Mariette Wolthers, Christiaan G.C. Van Baak, Iuliana Vasiliev, Marius Stoica, Francesca Sangiorgi, Jack J. Middelburg, Gareth R. Davies, Wout Krijgsman*

*Corresponding author for this work

Research output: Contribution to JournalArticleAcademicpeer-review

55 Downloads (Pure)

Abstract

During the so-called Messinian Salinity Crisis (MSC: 5.97-5.33 Myr ago), reduced exchange with the Atlantic Ocean caused the Mediterranean to develop into a “saline giant” wherein ∼1 million km3 of evaporites (gypsum and halite) were deposited. Despite decades of research it is still poorly understood exactly how and where in the water column these evaporites formed. Gypsum formation commonly requires enhanced dry conditions (evaporation exceeding precipitation), but recent studies also suggested major freshwater inputs into the Mediterranean during MSC-gypsum formation. Here we use strontium isotope ratios of ostracods to show that low-saline water from the Paratethys Seas actually contributed to the precipitation of Mediterranean evaporites. This apparent paradox urges for an alternative mechanism underlying gypsum precipitation. We propose that Paratethys inflow would enhance stratification in the Mediterranean and result in a low-salinity surface-water layer with high Ca/Cl and SO4/Cl ratios. We show that evaporation of this surface water can become saturated in gypsum at a salinity of ∼40, in line with salinities reported from fluid inclusions in MSC evaporites.

Original languageEnglish
Article number116029
Pages (from-to)1-12
Number of pages12
JournalEarth and Planetary Science Letters
Volume532
Early online date20 Dec 2019
DOIs
Publication statusPublished - 15 Feb 2020

Keywords

  • evaporites
  • gypsum
  • Mediterranean
  • Miocene
  • salinity
  • strontium

Fingerprint Dive into the research topics of 'Paratethys pacing of the Messinian Salinity Crisis: Low salinity waters contributing to gypsum precipitation?'. Together they form a unique fingerprint.

Cite this