Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides

S.G.A. van Assema, C.G.J. Tazelaar, G.T. de Jong, J.H. van Maarseveen, M. Schakel, M. Lutz, A.L Spek, J.C. Slootweg, K. Lammertsma

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

The copper-catalyzed Click reaction of phenyl azide with ethynylphosphine oxides provides new P-substituted triazoles. With tris(ethynyl)phosphine oxide this route affords a versatile scorpionate ligand that coordinates to RhCl
Original languageEnglish
Pages (from-to)3210-3215
JournalOrganometallics
Volume27
Issue number13
DOIs
Publication statusPublished - 2008

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