Phosphepines: Convenient Access to Phosphinidene Complexes

M.L.G. Borst, R.E. Bulo, C. Winkel, D. Gibney, M. Schakel, A.W. Ehlers, K. Lammertsma

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols. Copyright © 2005 American Chemical Society.
Original languageEnglish
Pages (from-to)5800-5801
JournalJournal of the American Chemical Society
Volume127
DOIs
Publication statusPublished - 2005

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