Phosphepines: Convenient Access to Phosphinidene Complexes

M.L.G. Borst; R.E. Bulo; C. Winkel; D. Gibney; M. Schakel; A.W. Ehlers; K. Lammertsma

doi:10.1021/ja050817y

Phosphepines: Convenient Access to Phosphinidene Complexes

M.L.G. Borst
, R.E. Bulo
, C. Winkel
, D. Gibney
, M. Schakel
, A.W. Ehlers
, K. Lammertsma

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols. Copyright © 2005 American Chemical Society.

Original language	English
Pages (from-to)	5800-5801
Journal	Journal of the American Chemical Society
Volume	127
DOIs	https://doi.org/10.1021/ja050817y
Publication status	Published - 2005

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abstract = "Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols. Copyright {\textcopyright} 2005 American Chemical Society.",

author = "M.L.G. Borst and R.E. Bulo and C. Winkel and D. Gibney and M. Schakel and A.W. Ehlers and K. Lammertsma",

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doi = "10.1021/ja050817y",

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T1 - Phosphepines: Convenient Access to Phosphinidene Complexes

AU - Borst, M.L.G.

AU - Bulo, R.E.

AU - Winkel, C.

AU - Gibney, D.

AU - Schakel, M.

AU - Ehlers, A.W.

AU - Lammertsma, K.

PY - 2005

Y1 - 2005

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AB - Reaction of o-diethynylbenzene with transition metal-complexed primary phosphines gives in a single base-induced step stable phosphepine complexes as confirmed by X-ray data. At 75-80 °C these phosphepines undergo clean cheletropic elimination of naphthalene to give transient carbene-like phosphinidene complexes that can be trapped in high yield by alkenes, alkynes, and alcohols. Copyright © 2005 American Chemical Society.

UR - https://www.scopus.com/pages/publications/17744397747

UR - https://www.scopus.com/pages/publications/17744397747#tab=citedBy

U2 - 10.1021/ja050817y

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SP - 5800

EP - 5801

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Phosphepines: Convenient Access to Phosphinidene Complexes

Abstract

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