(Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.−

F. Neumuller; R. Schmock; A. Kirmse; A. Voigt; A. Diefenbach; F.M. Bickelhaupt; K. Dehnicke

doi:10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

(Ph₄P)S₆—A Compound Containing the Cyclic Radical Anion S₆^.−

F. Neumuller, R. Schmock, A. Kirmse, A. Voigt, A. Diefenbach, F.M. Bickelhaupt, K. Dehnicke

Theoretical Chemistry

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).

Original language	English
Pages (from-to)	4580-4582
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	39
Issue number	24
DOIs	https://doi.org/10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G
Publication status	Published - 15 Dec 2000

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10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

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Cite this

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title = "(Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.−",

abstract = "Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).",

author = "F. Neumuller and R. Schmock and A. Kirmse and A. Voigt and A. Diefenbach and F.M. Bickelhaupt and K. Dehnicke",

year = "2000",

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day = "15",

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T1 - (Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.−

AU - Neumuller, F.

AU - Schmock, R.

AU - Kirmse, A.

AU - Voigt, A.

AU - Diefenbach, A.

AU - Bickelhaupt, F.M.

AU - Dehnicke, K.

PY - 2000/12/15

Y1 - 2000/12/15

N2 - Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).

AB - Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).

U2 - 10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

DO - 10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

M3 - Article

SN - 0570-0833

VL - 39

SP - 4580

EP - 4582

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 24

ER -