(Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.−

F. Neumuller, R. Schmock, A. Kirmse, A. Voigt, A. Diefenbach, F.M. Bickelhaupt, K. Dehnicke

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).
Original languageEnglish
Pages (from-to)4580-4582
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume39
Issue number24
DOIs
Publication statusPublished - 15 Dec 2000

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Anions
Negative ions
Conformations
Hydrogen
Crystals
tetraphenylphosphonium

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Neumuller, F. ; Schmock, R. ; Kirmse, A. ; Voigt, A. ; Diefenbach, A. ; Bickelhaupt, F.M. ; Dehnicke, K. / (Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.−. In: Angewandte Chemie International Edition in English. 2000 ; Vol. 39, No. 24. pp. 4580-4582.
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abstract = "Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).",
author = "F. Neumuller and R. Schmock and A. Kirmse and A. Voigt and A. Diefenbach and F.M. Bickelhaupt and K. Dehnicke",
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(Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.−. / Neumuller, F.; Schmock, R.; Kirmse, A.; Voigt, A.; Diefenbach, A.; Bickelhaupt, F.M.; Dehnicke, K.

In: Angewandte Chemie International Edition in English, Vol. 39, No. 24, 15.12.2000, p. 4580-4582.

Research output: Contribution to JournalArticleAcademicpeer-review

TY - JOUR

T1 - (Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.−

AU - Neumuller, F.

AU - Schmock, R.

AU - Kirmse, A.

AU - Voigt, A.

AU - Diefenbach, A.

AU - Bickelhaupt, F.M.

AU - Dehnicke, K.

PY - 2000/12/15

Y1 - 2000/12/15

N2 - Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).

AB - Two long S−S bonds link the two S3 fragments in the cyclic radical anion S6.−. This forms as orange‐red crystals with PPh4+ as the counterion in the reaction of sulfane with (tetraphenylphosphonium) hydrogen diazide. The anion has a chair conformation with C2h symmetry (see picture).

U2 - 10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

DO - 10.1002/1521-3773(20001215)39:24<4580::AID-ANIE4580>3.0.CO;2-G

M3 - Article

VL - 39

SP - 4580

EP - 4582

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

SN - 1433-7851

IS - 24

ER -