Preparation of a Ligand-Stabilized [P4O4]2+ via Controlled Hydrolysis of a Janus-Head Type Diphosphorus Trication

J.J. Weigand, K.O. Feldmann, A.K.C. Echterhoff, A.W. Ehlers, K. Lammertsma

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish
Pages (from-to)6178-6181
Number of pages4
JournalAngewandte Chemie International Edition in English
Volume49
DOIs
Publication statusPublished - 2010

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