Preparation of a Ligand-Stabilized [P4O4]2+ via Controlled Hydrolysis of a Janus-Head Type Diphosphorus Trication

J.J. Weigand; K.O. Feldmann; A.K.C. Echterhoff; A.W. Ehlers; K. Lammertsma

doi:10.1002/anie.201001363

Preparation of a Ligand-Stabilized [P4O4]2+ via Controlled Hydrolysis of a Janus-Head Type Diphosphorus Trication

J.J. Weigand
, K.O. Feldmann
, A.K.C. Echterhoff
, A.W. Ehlers
, K. Lammertsma

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Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	6178-6181
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	49
DOIs	https://doi.org/10.1002/anie.201001363
Publication status	Published - 2010

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10.1002/anie.201001363

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title = "Preparation of a Ligand-Stabilized [P4O4]2+ via Controlled Hydrolysis of a Janus-Head Type Diphosphorus Trication",

abstract = "A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems. {\textcopyright} 2010 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

author = "J.J. Weigand and K.O. Feldmann and A.K.C. Echterhoff and A.W. Ehlers and K. Lammertsma",

year = "2010",

doi = "10.1002/anie.201001363",

language = "English",

volume = "49",

pages = "6178--6181",

journal = "Angewandte Chemie International Edition in English",

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TY - JOUR

T1 - Preparation of a Ligand-Stabilized [P4O4]2+ via Controlled Hydrolysis of a Janus-Head Type Diphosphorus Trication

AU - Weigand, J.J.

AU - Feldmann, K.O.

AU - Echterhoff, A.K.C.

AU - Ehlers, A.W.

AU - Lammertsma, K.

PY - 2010

Y1 - 2010

N2 - A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - A door to new opportunities: The stepwise hydrolysis of a diphosphorus trication is an efficient method for the preparation of an unusual ligand-stabilized dication that contains a novel cationic [P4O4]2+ framework (see Scheme; gray C, blue N, red O, orange P). This approach demonstrates the potential of the diphosphorus trication as a source for phosphorus building blocks to be used in the construction of novel cationic ring and cluster systems. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

UR - https://www.scopus.com/pages/publications/77956041260

UR - https://www.scopus.com/pages/publications/77956041260#tab=citedBy

U2 - 10.1002/anie.201001363

DO - 10.1002/anie.201001363

M3 - Article

SN - 0570-0833

VL - 49

SP - 6178

EP - 6181

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

ER -

Preparation of a Ligand-Stabilized [P4O4]2+ via Controlled Hydrolysis of a Janus-Head Type Diphosphorus Trication

Abstract

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CCDC 766183: Experimental Crystal Structure Determination

CCDC 766184: Experimental Crystal Structure Determination

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Preparation of a Ligand-Stabilized [P4O4]2+ via Controlled Hydrolysis of a Janus-Head Type Diphosphorus Trication

Abstract

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Datasets

CCDC 766183: Experimental Crystal Structure Determination

CCDC 766184: Experimental Crystal Structure Determination

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