Prospects for high-resolution microwave spectroscopy of methanol in a Stark-deflected molecular beam

P. Jansen, I Kleiner, C. Meng, R. Lees, M.H.M. Janssen, W.M.G. Ubachs, H.L. Bethlem

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Recently, the extremely sensitive torsion-rotation transitions in methanol have been used to set a tight constraint on a possible variation of the proton-to-electron mass ratio over cosmological time scales. In order to improve this constraint, laboratory data of increased accuracy will be required. Here, we explore the possibility for performing high-resolution spectroscopy on methanol in a Stark-deflected molecular beam. We have calculated the Stark shift of the lower rotational levels in the ground torsion-vibrational state of CH
Original languageEnglish
Pages (from-to)1923-1930
JournalMolecular Physics
Volume111
Issue number12-13
Early online date5 Jun 2013
DOIs
Publication statusPublished - 2013

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