Protection of Ruthenium Olefin Metathesis Catalysts by Encapsulation in a Self-assembled Resorcinarene Capsule

L.J. Jongkind; M. Rahimi; D. Poole; S.J. Ton; D.E. Fogg; J.N.H. Reek

doi:10.1002/cctc.202000111

Protection of Ruthenium Olefin Metathesis Catalysts by Encapsulation in a Self-assembled Resorcinarene Capsule

L.J. Jongkind, M. Rahimi, D. Poole, S.J. Ton, D.E. Fogg, J.N.H. Reek

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimCatalyst encapsulation is examined as a means of increasing the productivity of olefin metathesis catalysts. Commercially available, cationic ruthenium metathesis catalysts were incorporated into a supramolecular resorcin[4]arene capsule. Encapsulation increased catalyst stability in water-saturated toluene, delivering higher metathesis yields than the parent, non-encapsulated Hoveyda catalyst in the same reaction medium.

Original language	English
Pages (from-to)	4019-4023
Journal	ChemCatChem
Volume	12
Issue number	16
DOIs	https://doi.org/10.1002/cctc.202000111
Publication status	Published - 20 Aug 2020
Externally published	Yes

Funding

We thank the European Research Council (ERC Adv. Grant 339786‐NAT_CAT) and NSERC of Canada for financial support.

Funders	Funder number
NSERC of Canada
Seventh Framework Programme	339786
European Research Council

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abstract = "{\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimCatalyst encapsulation is examined as a means of increasing the productivity of olefin metathesis catalysts. Commercially available, cationic ruthenium metathesis catalysts were incorporated into a supramolecular resorcin[4]arene capsule. Encapsulation increased catalyst stability in water-saturated toluene, delivering higher metathesis yields than the parent, non-encapsulated Hoveyda catalyst in the same reaction medium.",

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AU - Ton, S.J.

AU - Fogg, D.E.

AU - Reek, J.N.H.

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AB - © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimCatalyst encapsulation is examined as a means of increasing the productivity of olefin metathesis catalysts. Commercially available, cationic ruthenium metathesis catalysts were incorporated into a supramolecular resorcin[4]arene capsule. Encapsulation increased catalyst stability in water-saturated toluene, delivering higher metathesis yields than the parent, non-encapsulated Hoveyda catalyst in the same reaction medium.

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Protection of Ruthenium Olefin Metathesis Catalysts by Encapsulation in a Self-assembled Resorcinarene Capsule

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