SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS

J.W.G. Mastenbroek; F ARIESE; C GOOIJER; N.H. Velthorst; J.W. Hofstraat; WJM VANZEIJL

doi:10.1016/0045-6535(90)90007-G

SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS

J.W.G. Mastenbroek, F ARIESE, C GOOIJER, N.H. Velthorst, J.W. Hofstraat, WJM VANZEIJL

Research output: Contribution to Journal › Article

Abstract

High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.

Original language	English
Pages (from-to)	377-386
Number of pages	10
Journal	Chemosphere
Volume	21
Issue number	3
DOIs	https://doi.org/10.1016/0045-6535(90)90007-G
Publication status	Published - 1990

Cite this

Mastenbroek, J. W. G., ARIESE, F., GOOIJER, C., Velthorst, N. H., Hofstraat, J. W., & VANZEIJL, WJM. (1990). SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS. Chemosphere, 21(3), 377-386. https://doi.org/10.1016/0045-6535(90)90007-G

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abstract = "High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.",

author = "J.W.G. Mastenbroek and F ARIESE and C GOOIJER and N.H. Velthorst and J.W. Hofstraat and WJM VANZEIJL",

year = "1990",

doi = "10.1016/0045-6535(90)90007-G",

language = "English",

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AU - Mastenbroek, J.W.G.

AU - ARIESE, F

AU - GOOIJER, C

AU - Velthorst, N.H.

AU - Hofstraat, J.W.

AU - VANZEIJL, WJM

PY - 1990

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N2 - High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.

AB - High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.

U2 - 10.1016/0045-6535(90)90007-G

DO - 10.1016/0045-6535(90)90007-G

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JO - Chemosphere

JF - Chemosphere

SN - 0045-6535

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ER -

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10.1016/0045-6535(90)90007-G