SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS

J.W.G. Mastenbroek; F ARIESE; C GOOIJER; N.H. Velthorst; J.W. Hofstraat; WJM VANZEIJL

doi:10.1016/0045-6535(90)90007-G

SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS

J.W.G. Mastenbroek, F ARIESE, C GOOIJER, N.H. Velthorst, J.W. Hofstraat, WJM VANZEIJL

Research output: Contribution to Journal › Article › Academic › peer-review

Abstract

High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.

Original language	English
Pages (from-to)	377-386
Number of pages	10
Journal	Chemosphere
Volume	21
Issue number	3
DOIs	https://doi.org/10.1016/0045-6535(90)90007-G
Publication status	Published - 1990

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10.1016/0045-6535(90)90007-G

Cite this

@article{18666a0f3cfa49ee95edc5fe6139ff53,

title = "SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS",

abstract = "High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.",

author = "J.W.G. Mastenbroek and F ARIESE and C GOOIJER and N.H. Velthorst and J.W. Hofstraat and WJM VANZEIJL",

year = "1990",

doi = "10.1016/0045-6535(90)90007-G",

language = "English",

volume = "21",

pages = "377--386",

journal = "Chemosphere",

issn = "0045-6535",

publisher = "Elsevier Limited",

number = "3",

}

TY - JOUR

T1 - SHPOLSKII FLUOROMETRY AS AN INDEPENDENT IDENTIFICATION METHOD TO UPGRADE ROUTINE HPLC ANALYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS

AU - Mastenbroek, J.W.G.

AU - ARIESE, F

AU - GOOIJER, C

AU - Velthorst, N.H.

AU - Hofstraat, J.W.

AU - VANZEIJL, WJM

PY - 1990

Y1 - 1990

N2 - High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.

AB - High Performance Liquid Chromatography combined with fluorescence detection is routinely used in the Dutch Water Quality Survey to determine the Polycyclic Aromatic Hydrocarbons (PAH) contents of marine sediment samples. In this paper Shpol'skii spectroscopy is utilized to ascertain the identity and the purity of the peaks in the chromatogram by collection of several eluting fractions and subsequent spectroscopic analysis. The low temperature Shpol'skii technique provides high-resolution fluorescence spectra of PAHs that can serve as fingerprints. Thus, information concerning peak purity was obtained and the number of components identified was roughly doubled.

U2 - 10.1016/0045-6535(90)90007-G

DO - 10.1016/0045-6535(90)90007-G

M3 - Article

VL - 21

SP - 377

EP - 386

JO - Chemosphere

JF - Chemosphere

SN - 0045-6535

IS - 3

ER -