Shpol'skii spectroscopy and vibrational analysis of [N]phenylenes

C. Dosche, M.U. Kumke, F. Ariese, A.N. Bader, C. Gooijer, P.I. Dosa, S. Han, O.S. Miljanic, K.P.C. Vollhardt, R. Puchta, N.G. Hommes

Research output: Contribution to JournalArticleAcademicpeer-review


Vibrationally resolved fluorescence spectra of four angular [N]phenylenes were recorded with laser excited Shpol'skii spectroscopy (LESS) in an n-octane matrix at 10 K. In general, the same vibrational frequencies were observed in the fluorescence excitation and emission spectra, indicating that the geometries of ground and electronically excited state are very similar. Because of intensity borrowing from the S
Original languageEnglish
Pages (from-to)4563-4569
JournalPhysical Chemistry Chemical Physics - PCCP
Issue number20
Publication statusPublished - 2003


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