Shpol'skii spectroscopy and vibrational analysis of [N]phenylenes

C. Dosche, M.U. Kumke, F. Ariese, A.N. Bader, C. Gooijer, P.I. Dosa, S. Han, O.S. Miljanic, K.P.C. Vollhardt, R. Puchta, N.G. Hommes

    Research output: Contribution to JournalArticleAcademicpeer-review

    Abstract

    Vibrationally resolved fluorescence spectra of four angular [N]phenylenes were recorded with laser excited Shpol'skii spectroscopy (LESS) in an n-octane matrix at 10 K. In general, the same vibrational frequencies were observed in the fluorescence excitation and emission spectra, indicating that the geometries of ground and electronically excited state are very similar. Because of intensity borrowing from the S
    Original languageEnglish
    Pages (from-to)4563-4569
    JournalPhysical Chemistry Chemical Physics - PCCP
    Volume5
    Issue number20
    DOIs
    Publication statusPublished - 2003

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